含磷氮环氧树脂体系的合成、固化及其应用的研究.pdfVIP

⑧塑望盔兰堡主兰垡笙塞 摘要 本论文以开发新型无卤阻燃环氧树脂基覆铜板为目标，合成了两类结构 苯基亚甲基胺1一均三嗪(MFP)，考察了它们合成过程中的影响因素，用DSC 和原位红外光谱法探讨了MFP固化环氧树脂的固化反应机理。通过类似有机一 无机杂化的方法，探索了一种在环氧树脂体系中引入含氮三嗪环的新方法。考 察了覆铜板的压制工艺，测试了所制得的板材的阻燃、耐热等性能，进而探讨 了P、N的引入对板材性能的影响。经过分析测试证明，用MFP固化FD和ED 所制得的板材，其综合性能均能满足现今FR一4覆铜板的基本使用要求。 关键词：环氧树脂覆铜板无卤阻燃 ⑧塑坚叁兰堡土堂垡堡塞 ABSTRACT novel fire—retardant Inthis epoxy-basedcopper dissertation，severalhalogen—free laminates(CCL)were kindsof clad developed．Two method．Anovel ED)were different resins(FDand synthesizedby epoxy curingagent nitrogen—containing the was for synthesis epoxypolymers，and synthesizedpreparinghigh-performance withDGEBAhavebeen mechanismofMFPcured kineticsand kinetics，cure insitu DifferentialCalorimeter(DSC)andInfrared(FTIR)． investigatedby Scanning intothe resin was which Anewmethod epoxysystemexplored introducingnitrogen also theCCL issimilarto prepararation investigated organic／inorganichybird．We heatresistanceoftheCCL technics．The suchaS and fire—retardancy performances th