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《UO22+在Ca型石灰性土壤上的吸附行为 Study of UO22+ Sorption Onto Ca-Calcareous Soil》.pdf
第45卷第6期 原子能科学技术 V01.45,No.6
201 Atomic Scienceand 1
1年6月 Energy Technology Jun.201
UO三+在Ca型石灰性土壤上的吸附行为
张昱莹,范桥辉,王耀芹,许 江,牛智伟,吴王锁,许君政。
(兰州大学核科学与技术学院,甘肃兰州 730000)
摘要:采用静态批式法对u暖+在Ca型石灰性土壤上的吸附行为进行了研究,考察了接触时间、固液
比、pH和富里酸(FA)对U雠+在Ca型石灰性土壤上吸附和解吸的影响。研究结果表明,U暖+在Ca
型石灰性土壤上的吸附在约5h内可达吸附平衡,且符合准二级动力学模型。U嘎+在Ca型石灰性土
壤上的吸附为不可逆过程;但当FA浓度增至10mg/L时,U0;+在土壤表面的解吸作用明显增强。
关键词:石灰性土壤;Uol+;吸附;解吸;富里酸
中图分类号:0647.32 文献标志码:A 文章编号:1000—6931(2011)06—0651—06
of OntoCa-CalcareousSoil
Study
Uoi+Sorption
ZHANG
Yu—ying,FANQiao-hui,WANGJ
Yao~qin,XUiang,
NIU
Zhi—wei,WU
Wang—SUO。XUJun~zheng‘
(SchoolNuclearScienceand
of Technology,LanzhouUniversity,Lanzhou730000,China)
Abstract:Inorderto the behaviorof
investigatesorption Uo;+onCa—calcareoussoil,
thebatch was to theeffectsofcontact
techniqueperformedstudy time,solid—to-liquid
fulvic the
ratio,pH,andacid(FA)onofU0;+.Theresultsindicatethat
sorption
onCa-calcareoussoilcan in
’U0;+sorption achieve a shorttime,and
equilibriumvery
the accordswiththe kinetic
sorptionprocess pseudo-second-ordermodel.The
sorption
of Ca—calcareoussoilisan
U();+on irreversible th
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