《Scale-up synthesis and characterization of 2,6-diamino-3,5-dinitropyrazine-1-oxide》.pdfVIP

+ MODEL HOSTED BY Available online at ScienceDirect Defence Technology xx (2014) 1e6 /locate/dt Scale-up synthesis and characterization of 2,6-diamino-3,5-dinitropyrazine- 1-oxide Hai-bin WANG, Yan-hong WANG, Yong-xiang LI, Yu-cun LIU* School of Chemical and Environmental Engineering, North University of China, Taiyuan 030051, China Received 1 April 2014; revised 25 June 2014; accepted 14 July 2014 Abstract 2,6-diamino-3,5-dinitropyrazine-1-oxide (ANPZO), as an insensitive high explosive, with a high yield and excellent purity has been prepared at pilot plant scale by an improved method. The synthesized ANPZO is characterized by IR, laser granularity measurement, SEM and HPLC. The particle analysis revealed that the improved method could offer desired product with average particle size of 40 mm and high purity (98.45%). The experimental parameters exhibited that the detonation velocity of the formulation based on ANPZO was higher than that of the corresponding TATB formulation. The DSC curve showed that the exothermic decomposition of the product occurred at the temperature between 300.5 C and 360.4 C. Furthermore, the sensitivity test suggests its safe nature towards mechanical stimulus. Copyright © 2014, China Ordnance Society. Production and hosting by Elsevier B.V. All rights reserved. Keywords: ANPZO; Synthesis; Characterization; Detonation velocity; Sensitivity 1. Introduction