New Easy Method for the Monitoring of Hg Concentration in Fish, Using a Nanostructured Gold Electrode.pdfVIP

JournalofEnvironmentalScienceandEngineeringA4(2ol5、378-387 doi：10．17265／2162．5263／2015．07．006 New EasyMethodfortheMonitoringofHg ConcentrationinFish，UsingaNanostructuredGold Electrode AgneseGiacomino，GabriellaSchirinzi，AriannaPandi，M eryM alandrino，RosannaToniolo andOrnella Abollino0 J．DepartmentofDrugScienceandTechnology,UniversityofTorino,Torino10125，Italy 2．DepartmentofChemistry,UniversiytofTorino，Torino10125,ltaly 3．DepartmentofFoodScience,UniversityofUdine,Udine33100，Italy Abstract：Theapplicabilityofagoldnanoparticle-modifiedglassycarbonsensor(AuNPs—GCS、forthedeterminationofinorganic mercuryinfreshandcannedtunafishbysquarewaveanodicstrippingvoltammetry(SW-ASV)isdemonstrated．Mercurycontentin sampleTunaFishISPRA T22wasdeterminedtovaluetheaccuracyofthedetemr ination．Theconcentrationinthissampleisnot certified，so，theHgamountwasdeterminedalsowithatomicabsorptionspectroscopy(AAS)：hteresultsobtainedwithASVwerein goodagreementandconfirmed 1iteraturevaluereportedofrthissample．Then．realsamplesoftunafishwereanalyzed．The voltammetricnaalyseswereperfomredusingpreviouslyoptimizedconditions(depositionpotential0V，steppotentialO．004V， rfequency 15OHzandamplitude0．003V)．Medium exchangetechniquepermittedto eliminatepossiblematrix effects．The concentrations in therealsampleswere found to be in argeementwiht the common Hg 1evelsreported in literature ofr commercializedtunafishindifferem countries． Keywords：Goldnanopartielemodifiedglassycarbon sensor，squarewavestripping vohammetry，mercury，tunafish，medium exchange． 1．Introduction onto1and．surfacewaterandsoil． Heavymetalsare considered themostimportant There isincreasing concern aboutthequality of ofmr ofpollutionoftheaquaticenviromn entbecause foodsinseveralpartsofworld．Onesourceofriskfor