共振理论.pptVIP

Carbanions（碳负离子） —— Like a carbocation or a radical, a carbanion has three sigma-bond, but it also bears unshared electron pair. —— a simple carbanion is pyramidal. ( sp3-hybridized ) Carbanions —— When the carbanionic carbon is adjacent to a pi-system, sp2-hybridization is preferred so that the negative charge can be distributed by resonance throughout the p orital array. Some basic concepts A compound with delocalized electrons is said to have resonance（共振） The approximate structure using localized electrons is called a resonance contributor, a resonance structure, or a