取代螺环戊烷的电子轰击和化学电离正,负离子质谱有机化学.pdfVIP

有机化学(YOUJI HUAXU酌， 1987(5) , 342~346(研究论文〉 负离子质谱 取代螺环戊燎的电子轰击和化学电离正、 搏桂香气 林守2刻， 盛怀禹(中国科学院上海台·机化学研究所， t海〉 1:全水珍， 摘要z 本文报道了苯取代螺环戊烧衍生物的电子轰击(EI) 正离子和化学电离正、负离子(PNCI) 质 谱。通过亚稳离子测定，研究了该类化合物的裂解机理。在卤代螺环戊统的 EI 质谱中， 分子离子峰都 很弱，甚至不出现Mt 离子。具特征离子为[M -X]+、 [M - 2 X];和[M - X - HX1+ 0 CI 正离子谱有较 强的[M 句H]+、 [M - 2X]!和[M-Xy. CI 负离子谱的特征离子为[M+XJ-. 它们在多数情况下为基峰 离子，另外还出现HX X-离子。 或 2 叙调s 螺环化合物，电子轰击，化学电离源质谱法 Electron Impact (EI) and Chemical Ionization Positive and Negative Ion (PNCI) Mass Spectra of Substituted Spiropentanes FU Gui-Xiang飞、LlN Shou-Yuan , XU Yong-Zhen , SHENG Huai-Yu (Shanghaì instìtute 01 Organic Chemistry. Academìa Sinica, Shanghaì) AbstrJlct: The EI Positive and PNCI mass spectra of phenylspiropentanes were studied. By m臼ns of metastable ion measurements the mechanism of the cl臼vage of these compounds was studied in detaí l. In the EI sp四tra of halospiropentanes. the molecular ion peaks were so weak that the M-~ ion could not be observed. The characteristic ion peaks observed were [M-X了， [M -2 XJ i and [M -X -HXy. The CI positive ion spectra showed stronger [M +H了， [M- XJ+ and [M - 2Xy peaks. In the CI negative ion spectra , the characteristic ions were [M + Xr , which in most cases were the basic peak ions , and [HXr or X- ion was al随 found in these spectra. Descriptor: spiro compounds. electron bombardment. chemical ionization source mass liìpec- trometry Holmes