含苯并噻二唑的二维有机染料的合成与光伏性能研究有机化学.pdfVIP

DOI: 10.6023/cjoc201309006 研究论文 有机化学 Chinese Journal of Organic Chemistry ARTICLE 含苯并噻二唑的二维有机染料的合成与光伏性能研究 曹镇财 何 舟 邓利军 谭松庭* (湘潭大学化学学院 教育部环境友好化学与应用重点实验室 湘潭 411105) 摘要 通过引入烷基二噻吩苯并噻二唑窄带隙基元到 D-π-A 有机染料体系中, 设计并合成了两种二维结构的有机染料 DD2 和 DH2, 系统地研究了以烷基二噻吩苯并噻二唑基元作为侧基或桥联基元对染料敏化剂的光物理性能、电化学性 能和光伏性能的影响. 含有烷基二噻吩苯并噻二唑基元的这两种染料都具有较宽的吸收光谱. 在氙灯光源(100 −2 mW•cm , AM 1.5 G)下, 基于有机染料 DH2 和 DD2 的染料敏化太阳能电池的能量转换效率分别为 1.67%和 3.26%. 采 用鹅去氧胆酸(CDCA)共吸附剂优化后, 染料 DH2 表现出较好的抗聚集能力, 能量转换效率几乎没有变化; 而 DD2 的 能量转换效率提高到了 5.53%. 关键词 有机染料; 苯并噻二唑; 合成; 染料敏化太阳能电池 Synthesis and Photovoltaic Properties of Two Dimensional Organic Dyes Containing Benzothiadiazole Unit Cao, Zhencai He, Zhou Deng, Lijun Tan, Songting* (Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University , Xiangtan 411105 ) Abstract By introducing the narrow band gap unit (dithiophene-benzothiadiazole) to the organic dye system, two novel or- ganic dyes (DD2, DH2) with two-dimensional structures were designed and synthesized. The influence of dithiophene-ben- zothiadiazole unit acting as side chain or bridge group on the photophysical, electrochemical, and photovoltaic properties of the two dye-sensitizers was studied systematically. Two as-synthsized dyes with dithiophene-benzothiadiazole unit exhibited broad absorption spectra. Under one sun illuminati