基于中性铂炔基元的超分子有机金属凝胶研究进展有机化学.pdfVIP

DOI: 10.6023/cjoc201410046 综述与进展 有机化学 Chinese Journal of Organic Chemistry REVIEW 基于中性铂炔基元的超分子有机金属凝胶研究进展 范文佳 陈丽君* 杨海波* (华东师范大学化学系 上海市绿色化学与化工过程绿色化重点实验室 上海 200062) 摘要 作为一类经典的软物质材料, 超分子凝胶在催化、化学传感、药物释放等许多领域展示了广泛的应用前景. 最 近人们研究发现, 在基元砌块中引入金属特别是过渡金属之后, 所形成的有机金属凝胶在光电材料、催化、磁性等方 面具有独特的物理化学性质. 近年来, 电中性铂炔基元因其独特的线性结构、易合成及丰富的光物理性质在超分子化 学及材料科学中被广泛应用. 总结了基于中性铂炔基元的超分子有机金属凝胶的构筑及其功能研究进展, 主要包括以 苯撑共轭结构为核心骨架的铂炔有机金属凝胶以及官能团修饰的铂炔有机金属凝胶. 关键词 超分子化学; 自组装; 有机金属凝胶; 铂炔基元; π-共轭体系 Supramolecular Organometallic Gels Based on Neutral Platinum-Acetylide Moiety Fan, Wenjia Chen, Lijun* Yang, Haibo* (Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062) Abstract Supramolecular gels, as a family of classical soft materials, have received considerable attention because of their wide potential applications in catalysis, chemical sensing, drug delivery carrier, and many other areas. Recently, it was found that the introduction of metal moieties, especially the transition metal moieties into the gelator allows for the additional scope for tuning gel properties such as catalytic activity, magnetism, and photo- and electrochemistry. Neutral platinum-acetylide complex have been investigated in many respects from supramolecular chemistry to materials science