四硫富瓦烯及其衍生物在分子开关领域的研究进展有机化学.pdfVIP

2009 年第 29 卷 有 机 化 学 Vol. 29, 2009 第 1 期, 34～43 Chinese Journal of Organic Chemistry No. 1, 34～43 ·综述与进展· 四硫富瓦烯及其衍生物在分子开关领域的研究进展 朱玉兰*,a,b 周鑫鑫 a,b 尹起范 a 曹 丽 a a ( 淮阴师范学院化学系 江苏省低维材料化学重点建设实验室 淮安 223300) (b 延边大学理学院化学系 延吉 133002) 摘要 四硫富瓦烯(TTF)及其衍生物由于具有特殊的结构和性质, 在分子开关、分子传感器、光信息存储和非线性光学 等领域显示出诱人的应用前景. 综述了近几年 TTF 及其衍生物在分子开关领域的最新研究进展. 关键词 四硫富瓦烯; 合成; 分子开关; 分子识别 Advance in Tetrathiafulvalene and Its Derivatives as Molecular Switches Zhu, Yulan*,a,b Zhou, Xinxina,b Yin, Qifana Cao, Lia a ( Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials , Department of Chemistry, Huaiyin Teachers College, Huaian 223300) b ( Department of Chemistry, College of Science, Yanbian University, Yanji 133002) Abstract Tetrathiafulvalene (TTF) and its derivatives can be reversibly transformed into the radical cation •+ 2＋ TTF and dication TTF through either chemical or electrochemical oxidation. By using of this feature, TTF and its derivatives have been widely investigated for their potential use in molecular switches, molecu- lar sensors, optical information storage and nonlinear optics etc. This article reviews the recent progress in TTF and its derivatives as molecular switches such as fluorescence switch, photochromism switch, chiral switch and supramolecular switch. Keywords