基于四硫富瓦烯衍生物Langmuir-Blodgett膜的研究进展有机化学.pdfVIP

2009 年第 29 卷 有 机 化 学 Vol. 29, 2009 第 2 期, 197～205 Chinese Journal of Organic Chemistry No. 2, 197～205 ·综述与进展· 基于四硫富瓦烯衍生物 Langmuir-Blodgett 膜的研究进展 李洪启*,a 宋燕西 b 李秀梅 c (a 东华大学化学化工与生物工程学院 上海 201620) (b 东华大学环境科学与工程学院 上海 201620) (c 内蒙古通辽职业学院理工系 通辽 028000) 摘要 在简要介绍了 Langmuir-Blodgett (LB)膜的基础上, 主要依据制备 LB 膜的四硫富瓦烯(TTF)衍生物化学结构的不 同, 概括了基于两亲性 TTF 衍生物、非两亲性 TTF 衍生物、TTF 电荷转移(CT)复合物或盐、以及 TTF 金属络合物 LB 膜的制备、结构表征与性能研究进展. 介绍了基于 TTF 衍生物的 LB 膜在导电、化学及生物传感器、光学以及磁性方 面的应用, 并对基于 TTF 衍生物 LB 膜的发展进行了展望. 关键词 四硫富瓦烯; Langmuir-Blodgett ; 导电性; 光学; 传感器; 磁性 Advances in Study on Langmuir-Blodgett Films Based on Tetrathiafulvalene Derivatives Li, Hongqi*,a Song, Yanxib Li, Xiumeic (a College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620) (b College of Environmental Science and Engineering, Donghua University, Shanghai 201620) (c Department of Physics and Technology, Inner Mongolia Tongliao Vocational College, Tongliao 028000) Abstract After a brief introduction to Langmuir-Blodgett (LB) film, advances in preparation, structural characterization and property study of LB films based on amphiphilic tetrathiafulvalene (TTF) derivatives, non-amphiphilic TTF derivatives, TTF CT complexes or salts, and TTF metal complexes are reviewed mainly according to different structures of the TTF derivatives. Applications of LB films based on the TTF derivatives to electrical conduction, chemical sensors or biosensors