基于2,2’-联萘酚衍生物的荧光化学传感器对手性异构体选择性识别研究进展有机化学.pdfVIP

DOI: 10.6023/cjoc201306015 综述与进展 有机化学 Chinese Journal of Organic Chemistry REVIEW 基于2,2-联萘酚衍生物的荧光化学传感器 对手性异构体选择性识别研究进展 杨 丽a 徐括喜*,a 王晨娟a 王超杰*,b (a 河南大学化学化工学院 河南大学精细化学与工程研究所 开封 475004) (b 河南省天然药物与免疫工程重点实验室 开封 475004) 摘要 2,2-联萘酚是一个具有光活性的轴手性化合物, 近年来, 它已成为构筑多种多样的手性化学传感器的基本骨架 之一. 很多文献报道了近年来众多基于 2,2-联萘酚的荧光化学传感器被广泛的设计和合成并表现出对手性氨基酸、氨 基醇, α-羟基羧酸及其衍生物和其他化合物表现出很高的选择性和灵敏度. 综述了以 2,2-联萘酚衍生物作为化学传感 器在对手性异构体的选择性识别中的应用的最新的研究进展. 关键词 手性异构体; 2,2-联萘酚; 化学传感器; 荧光 Progress in Fluorescent Chemosensors for Chiral Enantiomer Recognition Based on 2,2-Naphthol Derivatives Yang, Lia Xu, Kuoxi*,a Wang, Chenjuana Wang, Chaojie*,b a ( Institute of Fine Chemical and Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004) b ( Key Laboratory of Natural Medicine and Immuno-Engineering of Henan Province, Kaifeng 475004) Abstract Being an axial chiral compound with optical activity, 2,2-naphthol (BINOL) has become one of the basic units for constructing various chiral fluorescent chemosensors in recent years. According to the literatures, chiral BINOL derivatives chemosensors carry out highly enantioselective, sensitive recognition of amino acid and its derivatives, chiral amino alcohols, and α-hydroxycarboxylic acids. In this progress, BINOL derivatives as enantioselective chemosensors for chiral enantiomers are summarized. Keywords chiral enantiomer; 2,2-naphthol