烷基芳基环聚硅烷[RArSi)n,n=5,6]的合成及其波谱性质有机化学.pdfVIP

有机化学(YOU.n HUAXUE 1988, 8 , 037~041 研烧简报 烧基劳基环骤磕蜿[(RArSi)ll ， lι=5 ， 6J的合成及其波谱性质 刘维泰、陈珊妹* 〈中国科学院兰州化学物理研究所，兰州) Synthesis and Spectral Properties of AlkyIarylcyclopolysilanes [(RArSi)n ,n = 5 ,6J L1U Wei-Tai , CHEN Shan-Mei (tanzhou Institute of Chemical Physics , Academiα Sinica， Lαnzhou) Abstract: The coupling reaction of alkylaryldichlorosi1ane in THF with an excess of lithium in the presence of hexaphenyldisi1ane or trimethyltriphenyldisi1ane gave the major products , (PhMeSi) e(1), (p-MeC H SiMe)6 (2) , (o-MeC H SiMe)5(3). (PhCH,,- 6 4 e 4 SiMe) 6 (肘， (PhEtSi)6 (5) and (PhSiCHJ! CH=CH )6 (韵， which , except 1, were new z compounds and hιve been identified and characterized with NMR , IR. MS and UV spectroscopy. HPLC identification of the product mixtures of (PhMeSi) revealed that various products with different ring size and geornetric isomerization of the substituents might also exist depending on the mole ratio of starting materials and presence or absence of the catalyst. Descriptor: cyc1opolysilane , coupling reaction. preparation. spectra 半个多世纪前Kipping 最先报道了二芳基 与碱金属反应制得。对于硅原 子J-_ 取 ~2由C1 2 1 2 环聚硅皖(ArzSi)71 的合成，其中 Ar =Ph , p-- 相应的代了不同基团的了不硅;院(R R Si) .，虽 MeC H n = 4, 5, 6[1.2] 。但是直到四十年后， 然也可以用类似方法合戚，但是反应产物复杂， 6 它们的结构才由 Gilman 证明[3] 。迄今研究最 其中含有不同大小的环和不同构型的几何异构