双核烷基咪唑过氧磷钨酸盐相转移催化剂合成及催化烯烃环氧化性能.pdfVIP

Chinese Journal of Catalysis 34 (2013) 2236–2244 催化学报 2013年 第34卷 第12期 |   a v a i l a b l e  a t  w w w . s c i e n c e d i r e c t . c o m   j o u r n a l  h o m e p a g e :  w w w . e l s e v i e r . c o m / l o c a t e / c h n j c   Article  Synthesis of dicationic alkyl imidazolium peroxopolyoxotungsten‐ based phase transfer catalyst and its catalytic activity for olefin epoxidation Jianghao Wu, Pingping Jiang*, Yan Leng, Yuanyuan Ye, Xiaojie Qin The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu, China   A R T I C L E I N F O A B S T R A C T Article history: Peroxopolyoxotungsten‐based hybrid catalysts modified by dicationic long‐chain alkyl imidazolium Received 17 June 2013 cations have been synthesized and characterized. The catalytic activity of the catalysts was meas‐ Accepted 21 August 2013 ured for the epoxidation of olefins with H O. These catalysts proved to be high catalytic activity 2 2 Published 20 December 2013