极谱与伏安法英文版PolarographandVolatmmetry概述.pptVIP

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极谱与伏安法英文版PolarographandVolatmmetry概述.ppt

4 Polarography and Voltammetry (极谱分析与伏安分析法) 4.1 Apparatus and Principle of Polarography 4.1.1. Terminology Voltammetry:Measurement of a current at a microelectrode as a function of the potential( versus a reference electrode) of the microelectode. Polarography: A branch of voltammetry in which working electrode consists of dropping-mercury electrode (DME) (滴汞电极) 4.1.2. Apparatus of Polarography 4.1.3. Polarographic wave (极谱波) Shape of the i-e curve of polarography (2)Formation of the polarographic wave -② Residual current (残余电流): ir ② Decomposition potential: where Cd2+ could be re

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