有机化学对映异构要点解读.ppt

第3章 对映异构 Types of Chirality Definitions Definitions Chiral Atom (Stereogenic Centre) Any atom surrounded by 4 different groups. The term chiral refers to individual molecules. It does not tell you anything about the enantiomeric purity of a substance. Racemates are made up of chiral molecules. Enantiomerically Pure All molecules in the sample are the same enantiomer. Diastereomers Stereoisomers which are not enantiomers Diastereoselectivity Preference for one diastereomer of product over another. Enantioselectivity Preference for one enantiomer of product over the other, achieve