《Electrochemical studies of U(VI)U(V) in saturated Na2CO3 solution at gold nanoparticles embedded CTA-modified electrode》.ppt

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2017-05-13 发布于浙江
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《Electrochemical studies of U(VI)U(V) in saturated Na2CO3 solution at gold nanoparticles embedded CTA-modified electrode》.ppt

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文献汇报 ——赵梦婷 2015-3-26 试剂与仪器硝酸铀酰、三乙酸纤维素、Na2CO3、 NaBH4 、二氯甲烷电化学工作站（CHI 440A）三电极系统：金电极为工作电极、铂丝为辅助电极、Ag/AgCl电极为参比电极紫外-可见分光光度计、原子力显微镜（AFM）、X射线衍射（XRD） AuNPs-CTA修饰电极的制备将CTA和Aliquat-336（3:1）溶解在二氯甲烷中。取10μL的混合物滴涂在裸金电极上，直至二氯甲烷完全挥发后，再在HAuCl4溶液中浸泡一晚上。用二次水彻底清洗，然后浸泡在NaBH4溶液（减少AuCl4-）中搅拌，形成金纳米粒子，即得到AuNPs-CTA修饰电极。 AuNPs-CTA modified electrode was prepared by drop-casting 10μL of dichloromethane solution containing CTA and Aliquat-336 in 3:1 ratio on surface of bare Au electrode. The electrode was rested till the complete volatilization of dichloromethane, and then it was dipped in a solution of HAuCl4 overnight. It was thoroughly washed with water and HAuCl4-loaded CTA modified electrode was dipped into sodium borohydride solution under stirring to reduce AuCl4- ions to gold nanoparticles. * * Electrochemical studies of U(VI)/U(V) in saturated Na2CO3 solution at gold nanoparticles embedded CTA-modified electrode Fig.1. UV-visible spectrum of AuNPs-CTA membrane Fig.2. XRD spectrum of AuNPs-CTA membrane Fig.3. Noncontact AFM images (2D, 3D and profilogram) of AuNPs-CTA membrane Fig.4. Cyclic voltammograms of the AuNPs-CTA modified electrode and bare gold electrode in 1M H2SO4 solution .Scan rate=100mV/s. Fig.5. Cyclic voltammograms of 5mM UO22 + in saturated Na2CO3 at bare gold and AuNPs-CTA modified electrodes .Scan rate=50mV/s. Fig.6. Chronoamperometric transients of 5mM UO2 2+ in saturated Na2CO3 at bare gold and AuNPs-CTA modified electrodes upon the application of a reductive potential step from 0.6 to 1.2V. Fig.7. Plot of ipc vs. υ1/2 (scan rate from 20 to 400mV/s in intervals of 20mV/s) on (A) bare gold and (B) AuNPs-CTA modified electrodes (C) Plot of Epc vs.logυ at higher scan rates (120 to 400mV/s) Solution: 5mM UO2 2+ in saturated Na2CO3 Fig.8. Impedance spectra (Nyquist plots) of bare gold and AuNPs-CTA modified electrodes. Data were recorded in the presence of 2.5mM [Fe(CN)6] 3-/ 4- with an a.c. poten