Al_2O_3改性对中高磷转炉渣中磷富集行为的影响_江露.docxVIP

Al2O3改性对中高磷转炉渣中磷富集行为的影响江露刁江闫小满张涛李鸿乂谢兵（重庆大学材料科学与工程学院，重庆市,沙坪坝区,邮编 400044）摘要 为了有效富集中高磷转炉渣中的磷，通过Al2O3熔融改性研究了磷富集的行为，用矿相显微镜和SEM+EDS并结合XRD观 察了原始模拟渣和改性渣的微观形貌，P元素的分布及赋存形式的变化。并用热力学软件（Factsage 6.3）理论计算和分析Al2O3改性机理。结果表明：n2CaO·SiO2–3CaO·P2O5固溶体(nC2S–C3P)是由先期析出的Ca3(PO4)2和Ca2SiO4反应生成。在1623K条件下， 随着渣中Al2O3的增加，渣中先期析出的n2CaO·SiO2-3CaO·P2O5（以下简记nC2S-C3P）固溶体与+Al2O3不断反应生成钙铝黄长石 和高磷固溶体(n′C2S-C3P) (n′＜n)，先期析出的nC2S-C3P固溶体会随着Al2O3的增加而逐渐减少甚至消失，如渣中Al2O3进一步增 加或过量，产物甚至出现C3P。利用Al2O3对中高磷转炉渣改性为钢渣的回收利用奠定基础。关键词中高磷渣nC2S-C3P固溶体Al2O3改性P富集Influence of Al2O3 Modification on Phosphorus Enrichment in High Phosphorus SlagJiang Lu, Diao Jiang, Yan Xiaoman, Zhang Tao, Li Hongyi, Xie Bing(College of Materials Science and Engineering, Chongqing University, Shapingba, Chongqing 400044)Abstract The phosphorus enrichment behavior was investigated by slag modification with Al2O3. The mineral phase of the original slagand modified slags were measured by mineral phase microscope, SEM+EDS and XRD. The mechanism of Al2O3 modification was dis-cussed according to the thermodynamic theory analysis software (Factsage version 6.3). The results show that n2CaO·SiO2–3CaO·P2O5 (nC2S–C3P) solid solution was generated by the precipitation of Ca3(PO4)2 phase and Ca2SiO4 phase. High phosphorus solid solution (n′C2S-C3P) was generated by the continuous reaction of n2CaO·SiO2-3CaO·P2O5 (n′＜n) solid solution and Al2O3 under 1623K. The amount of early precipitated solid solution (nC2S-C3P) was reduced and even disappeared with the increasing of Al2O3. If the addition of Al2O3 is excess, the product is even Ca3(PO4)2, which was demonstrated that the addition of Al2O3 has a positive influence on the P en-richment. This finding may open up new opportunities for recovery of P from high phosphorus slag.Key wordshigh phosphorus slagnC2S-C3P solid solutionAl2O3 modificationP enrichment1 前言近年来，世界范围内有限的富矿资源日益减少；高磷、低品位铁矿将逐渐开发利用。因此，高磷铁矿的利用会导致铁水中磷含量的上升；在炼钢过程中大部分含量的磷会进入到渣中，进而渣中的磷含量会增加。 当前，高磷钢渣的主要利用方向是为钢渣磷肥提供原料[1-7]。通常，普通的BOF转炉渣中P2O5含量在1-3%，当 铁水中的磷含量为