05-Hydogen Storage materials.ppt

1) Zr1-xTixCr2 3.3 Zr-based multi-component alloys As x = 0~0.2, capacity H/M = 4.0~4.5 As x = 0.9~1.0, capacity H/M = ~3.3 2) Zr1-xTixMn2 As x = 0~0.6, capacity H/M = 3.6~4.0 As x = 0.6~1.0, capacity H/M = 0.3~3.6 蘑颜阁居挺分熬枫究寇误沁黑窿析红衣询俞幸贰卒界时范却琴诬涟回谅项05-Hydrogen Storage materials05-Hydrogen Storage materials 3.3 Zr-based multi-component alloys 3) Zr(Cr1-xMx)2 (M=Fe, Co, Ni, ……) As x↑, → capacity H/M↓ 4) Zr(Cr1-xVx)2 As x↑, → capacity H/M↑ As x↑, → Peq↓, |?H| ↑ As x↑, pressure plateau → steeper 夏宿盲朽尿凌语窖展幸沪负却弯慷筹副柞并水砾啼二拓验杀鸥配渡焙吉汉05-Hydrogen Storage materials05-Hydrogen Storage materials 1) ZrNix (x=0~5) 3.4 Zr-based electrode alloys As x↓, charge capacity ↑, but dischargeability↓ Zr-based electrode alloys contains Ni element due to its electro-catalysis As x=1.2, the alloy has a highest discharge capacity Cmax= 210 mAh/g 馅陪夷馒七德鞠篡颅榆泅稽晒宪稚呀噬赵陇退笺润窗距既斜篙蓑贾操阮之05-Hydrogen Storage materials05-Hydrogen Storage materials 3.4 Zr-based electrode alloys 2) Zr-V-Ni alloys (i) Zr(V1-xNix)2 (x=0.1~1.0) As x↑, charge capacity↓ As x=0.67, the alloy has only a single C15 type Laves phase and a highest discharge capacity Cmax= 298 mAh/g at 16 mA/g. 杨索普度渴俭磺盐营荚绒常艇刽之盐屯奔率寸号祥检砌套滔娜挪袜段交凉05-Hydrogen Storage materials05-Hydrogen Storage materials (ii) Zr(V0.33Ni0.67)2+? ( ? = 0 ~ 1.0 ) As ? ↑, charge capacity↓ 3.4 Zr-based electrode alloys As ? =0.2~0.4, the alloy has a highest discharge capacity Cmax= 311 mAh/g. 秋殿驹笆子坏揖贴目杜亮挚振齐狠傈找肺随疟乒涅到既侄注处蟹异友状读05-Hydrogen Storage materials05-Hydrogen Storage materials 3.4 Zr-based electrode alloys (iii) Zr(V0.25Ni0.75) ? ( ? = 1.0 ~ 4.0 ) The alloys have a main phase of C15 type Laves phase. As ?≤ 2.5, only a single C15 type Laves phase; As ? 2.0 (super-stoichiomertic), V → A side; As ? =2.0, discharge capacity Cmax= 394 mAh/g at 5 mA/g; As ? =3.0, discharge capacity Cmax= 800 mAh/g at 2 mA/g and Cmax= 400 mAh/g at 20 mA/g. 稻涣档鸿晓斜眩份怒肖是音贴闰尧仿潮许包荤值宫馆鲤确嘴凯隋缕沙绕蚤05-Hydrogen Storage materials05-Hydrogen Storage materials 3