氨基和聚醚改性有机硅柔软剂对织物去污性能的影响-中国日用化学.docVIP

氨基和聚醚改性有机硅对织物去污性能的影响 （浙江理工大学 材料与纺织学院，浙江 杭州 310018） 摘要：本文以纺织柔软整理中常见的氨基和聚醚改性有机硅为例，研究了有机硅柔软剂对织物去污性能的影响。从织物表面能、有机硅表面含量、有机硅与织物及污渍的结合等分析了织物去污指数变化的原因。织物经过氨基改性有机硅处理后，其去污指数有所下降，主要原因有三点：1）氨基改性有机硅处理后的织物疏水性增强、表面能降低，使得在洗涤过程中洗涤液不易进人织物与污渍之间；2）氨基改性有机硅由于本身的正电性使其在织物表面的吸附量增加，以及提高了其与污渍的结合力；3）氨基改性有机硅具有较好的耐洗性，在洗涤过程中不易和污渍一起脱落。相反，织物经聚醚改性有机硅处理后，织物的亲水性提高，由于其电荷间的排斥，有机硅和织物的结合较弱，且在洗涤过程中易和污渍一起洗脱。因此，织物经聚醚改性有机硅处理后洗涤效果得以提高。 关键词：氨基有机硅；聚醚有机硅；织物去污指数；织物表面能；有机硅含量分析 Impact of Amino or Polyether Modified Silicone Softeners on Fabric Stain Removal Performance PEI Liu-jun, GE Hua-yun, AN Yuan-yuan, WANG Ji-ping (College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China) Abstract: Using amino or polyether modified as examples, impacts of silicone softeners on fabric stain removal performance are studied. It was found that fabrics treated with amino modified silicones had poorer stain removal index while fabrics treated with polyether modified silicone had improved the performance. With analysis of fabric surface energy, Si content, wash fastness and silicone-stain interaction, silicone’s impacts on the fabric stain removal performance are mainly concluded from following three areas: 1) surface energy of silicone treated fabrics, the higher the surface energy, the better is the stain removal performance; 2) cationic charge of amino modified silicones create strong interaction between silicones and stains, leading poor stain removal index; 3) due to silicone-stain interaction, stains may be washed away with silicone on fabric surface. Poorer silicone wash fastness leads to better stain removal performance. Key words: amino silicone; polyether silicone; stain removal index; the surface energy; silicone content 随着我国经济的发展和生活水平的不断提高，人们对纺织品的服用性能要求越来越高，纺织品的附加值也不断的增加[1-2]。有机硅的柔软整理已成为最为普遍的纺织品整理之一，用以提高织物的服用性能。用以纺织品的、基于含氟的化合物易去污整理剂已使用多年，然而，用碳氟化合物处理后的织物，其手感粗糙且穿着较不舒服[3-5]。对棉织物整理而言，含酰胺基、聚氧乙烯基以及哌啶官能团的有机硅对其具有良好的抗湿沾污性能，但对干态的沾污性能效果比较小。现在，将含氟的聚合物与有机硅混合使用的研究比较多，聚硅氧烷主链与具有ABA结构