ppt课件-intermolecular forces1- universityof birmingham（分子间forces1 -伯明翰大学）.pptVIP

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ppt课件-intermolecular forces1- universityof birmingham（分子间forces1 -伯明翰大学）.ppt

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ppt课件-intermolecular forces1- universityof birmingham（分子间forces1 -伯明翰大学）

CHM2S1-A Intermolecular Forces Dr R. L. Johnston Handout 1: Introduction to Intermolecular Forces I: Introduction Evidence for Intermolecular Forces The nature of Intermolecular Forces Electric Multipoles II: Intermolecular Interactions Types of Intermolecular Interactions Many-Body Energies Total Energy Comparison of Intermolecular Forces Overview Intermolecular forces are critically important in determining the properties of matter. We will discuss the forces that exist between atoms and molecules. Evidence (taken from thermodynamic, structural and other experimental studies) will be provided for the existence of intermolecular forces. The various types of intermolecular forces will be described: including the origin of the forces and their distance-dependence. A more detailed discussion of the consequences and implications of intermolecular forces will follow. Finally, the “anomalous” properties of water and the importance of hydrogen bonding and the “hydrophobic effect” in biological systems will be analysed. Learning Objectives To recognise the importance of intermolecular forces in determining the physical properties of matter; To know the experimental evidence for the existence of intermolecular forces; ? To understand the origins of the various types of intermolecular forces; To know the distance-dependence of intermolecular forces of various types; To understand the origins of the so-called “anomalous” properties of water. To recognise the importance of hydrogen bonding and the hydrophobic effect in biological systems. References Fundamentals P. W. Atkins, The Elements of Physical Chemistry (3rd edition), OUP, Oxford, 2000. P. W. Atkins, J. de Paula, Atkins Physical Chemistry (7th edition), OUP, Oxford, 2001. K. A. Dill, S. Bromberg, Molecular Driving Forces, Garland Science, New York, 2003. More Advanced M. Rigby, E. B. Smith, W. A. Wakeham, G. C. Maitland, The Forces Between Molecules, OUP, Oxford, 1986. A. J. Stone, The Theory of In