Schottky contacts of (Au, Pt)nanotube-titanates for fast response to NO2 gas at room temperature.pdfVIP

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Schottky contacts of (Au, Pt)nanotube-titanates for fast response to NO2 gas at room temperature.pdf

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Schottky contacts of (Au, Pt)nanotube-titanates for fast response to NO2 gas at room temperature.pdf

Sensors and Actuators B 244 (2017) 941–948 Contents lists available at ScienceDirect Sensors and Actuators B: Chemical journal homepage: /locate/snb Schottky contacts of (Au, Pt)/nanotube-titanates for fast response to NO2 gas at room temperature Do Thi Thu a, Hoang Thi Hien b,c, Do Thi Anh Thu a, Pham Quang Ngan a, Giang Hong Thai a, Chu Van Tuan b, Tran Trung b, Ho Truong Giang a,? a Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Vietnam b Hung Yen University of Technology and Education, Khoai Chau, Hung Yen, Vietnam c Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Vietnam article info Article history: Received 24 October 2016 Received in revised form 4 January 2017 Accepted 5 January 2017 Available online 6 January 2017 Keywords: Nanotube titanates Schottky contact Room temperature gas sensor abstract In this work, NO2 sensing characteristics of the sensors based on Schottky contacts between metal electrodes (Au, Pt) and nanotube titanates (NaxH2?xTi3O7) for room temperature operation were investigated. The nanotube titanates (NTT) with 10 nm in diameter were synthesized by a typical hydrothermal method. The sensors were fabricated with different con?gurations of Pt/NTT/Pt, Au/NTT/Au and Au/NTT/Pt for analyzing effect of the Schottky contacts (Au, Pt)/NTT on gas-sensing performance. The NO2 sensing results of the sensors indicated that the synthesized nanotube titanates were p-type semiconductor and the interface Au/NTT had large NO2 sensitivity in comparison with the interface Pt/NTT. High selectivity of the sensor Au/NTT/Pt to NO2 gas was also presented by cross-sensing investigation to some gases such as NO, NH3, H2, CO and C3H8. Additionally, it was found that the sensor Au/NTT/Pt exhibited high sensitivity and fast response/recovery times in low concentration range of NO2 gas (0–10 ppm) at room temperature. The ga