醋酸甲酯水解催化反应精馏模拟+.pdf

醋酸甲酯水解催化反应精馏模拟 李柏春，娄孟坛，孙莉君，张克强 （河北工业大学, 化工学院，天津 300130） 摘要：催化反应精馏应用领域的开拓和应用技术的研究近年来受到越来越多的重视，并在一些工业领域取得 了成功应用。在聚乙烯醇工业生产过程中，醋酸甲酯回收工艺是采用固定床反应器将醋酸甲酯水解为甲醇和 醋酸，该过程水解率低（一般为 25％左右），造成大量醋酸甲酯在系统中循环。本文针对醋酸甲酯水解催化 反应精馏新工艺，建立了非平衡级反应精馏速率模型和过程模拟的计算方法，通过模拟计算考察了回流比、 进料水酯比、进料位置等过程参数对醋酸甲酯水解反应精馏过程的影响。模拟结果表明，水酯比2.0～4.0、 回流进料比3.0～4.0、进料位置在反应精馏段中部时转化率可达70％以上，能够满足PVA回收工艺的需要， 得到了下一阶段工业化试验的工艺条件，为工业化生产提供了技术支持。 关键词：非平衡级速率模型；模拟；反应精馏 Process Simulation on Catalytic Distillation of Methyl Acetate Hydrolysis Li Baichun, Lou Mengtan, Sun Lijun, Zhang Keqiang (School of chemical Engineering and Technology ,HeBei University of Technology, TianJin 300130) Abstract:The exploitation and application of catalytic distillation technique have bee- n paid much attention.Some achievements have been acquired in some industry fields. Fixed bed reactor is adopted in methyl acetate recovery technology in the polyvinyl alcohol(PVA)industry production process.The conversion of methyl acetate is low(ab- out 25%)in the process and lots of methyl acetate circulate in the system,which lead to lager quantity of energy consumed. In this text,a non-equilibrium rate model and the calculation method based on the process of methyl acetate hydrolysis are established. The influences of some parameters on conversion and concentration of acetic acid in bottom feed were investigated.For example the mole ratio of water feed to methyl acetate feed(H O/MeOAc), reflux feed to methyl acetate feed and the feeding position 2 and so on.The result show that when the value of H O/MeOAc is 2.0~4.0,the value of 2 reflux feed to methyl acetate feed is 3.0~4.0 and the feeding position is in the middle of catalytic distillation,the conversion of methyl acetate is higher than 70%.It can meet the need of the process of PVA recover