阳离子微粒氢氧化镁铝的合成及其微粒助留作用.pdfVIP

阳离子微粒氢氧化镁铝的 合成及其微粒助留作用 王松林刘温霞 (山东轻工业学院制浆造纸工程省级重点学科，济南，250100) 摘要：混合二元金属氢氧化物(又称水滑石)由于其自身所带的强正电性和特殊的晶体结构．可 以与阴离子聚丙烯酰胺复配应用到造纸湿部助留中。本文采用共沉淀法合成各种不同阴离子和 不同镁铝摩尔比例的氢氧化镟铝水滑石胶体，并对其化学结构式，微粒粒径，Zeta电位等进行测量 分析。由实验可以发现镁铝型水滑石含永久的正电性，并且可以形成纳米级微粒，其带电情况和 微粒粒径会随镁铝摩尔比例的不同和合成过程而变化。应用动态滤水仪测定氢氧化镁铝胶体和 阴离子聚丙烯酰胺复配作用可以显著提高浆料的留着率。而微粒粒径，微粒Zeta电位及其他性质 都会对留着效果产生影响。 关键词：氢氧化镁铝水滑石微粒助留 Using Colloidal Layered Double Hydroxides as Cationic Microparticulate Component Wang Songlin Liu Wenxia，Shandong (Institute of Lisht Industry，Jinan 250100，People§Repubhc of China) Abstract：Layered double hydroxides consisting of layers with cationic charges may be potential candi- dates of cationic micmparticles forming synergetic retention effect with anionic polyacrylamide．In this work，the layered double hydroxides with various molar ratios of Mg／A1 were synthesized by CO—precipi— tation of magnesium chloride and aluminum chloride and peptized by intense washing with water．The chemical formula，particle size，zeta potential of the layered double hydroxide were analyzed．It was found that positively charged magnesium aluminum hydroxide with particle diameter in nanoparticle size could be prepared．The Zeta potential and particle size vary with the feed molar ratio of Mg／A1 and the peptizing process，respectively．The Zeta potential is also pH dependent．The retention experiments Car一 五ed out on DDJ show that when used together with anionic polyacrylamide．the positively charged colloi· dal double hydroxide greatly improves the retention of reed pulps．The chemical formula，particle size and Zeta potential of the colloidal double hydroxide all affect its retention behavior． Keyword：layered double hydroxides hydrotalcite micmpartiele retention aid． 典型的微粒助留体系由阳离子聚合物和带负电荷的无机或有机微粒组成，其对纸料絮聚所形 一96— 成的絮聚体小面致密，具有可逆性”。，可同时提高纸料的冒着与滤水性能，成纸透气性好，并可改 善成纸的匀度，其中微粒组分又是获得微粒助留作用及相关效益的关键，因此，有关微垃助留体系 的改进多以新型徽粒组分的研究有关：如在离散型胶体基础上开发的高结构肢体二氧化硅o。，在 保留其高电荷密度的同时，通过原生颗粒间的枝状交联增加了腔体二氧化硅的粒子尺寸，进而提 高了架桥能力。有机阴离子微粒’则由于更容易控制其电荷密度和粒度．并可在微粒表面接枝柔 韧的阴离子长链，而成为更加有效的微粒助留组