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Discovery of a new type of organic ferroelectric materials in natural biomass
Dynamic Article LinksCJournal of
Materials Chemistry
Cite this: J. Mater. Chem., 2011, 21, 14599
/materials PAPER
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View Online / Journal Homepage / Table of Contents for this issueDiscovery of a new type of organic ferroelectric materials in natural biomass
dehydroabietylamine Schiff bases?
Yan Sui,*ab Dong-Sheng Liu,ab Rong-Hua Hua and Hong-Mei Chena
Received 13th October 2010, Accepted 4th January 2011
DOI: 10.1039/c0jm03461dThree kinds of Schiff bases, 5-chlorosalicylidene dehydroabietylamine (ClDHA), 5-bromosalicylidene
dehydroabietylamine (BrDHA) and 5-nitrosalicylidene dehydroabietylamine (NODHA), have been
prepared and characterized by elemental analyses, IR, circular dichroism (CD), and X-ray structural
analyses. Ferroelectric, dielectric and NLO properties are reported for the first time in cheap natural
biomass resource dehydroabietylamine derivatives and their ferroelectric properties can be easily tuned
through the substituents of the aromatic aldehyde. With the increase in electron-withdrawing
properties of the substituents from –Br to –Cl and then –NO2, the Ps values or the ferroelectric
properties gradually increased.Introduction
Ferroelectricity is one of the major subjects in the field of
materials science due to its wide applications in ferroelectric
random-access memories (FeRAM), switchable nonlinear
optical devices, electro-optical devices, and light modulators.1
Since the discovery of ferroelectricity in Rochelle salt in 1920,
many efforts have been ongoing towards the design and synthesis
of noncentrosymmetric ferroelectric compounds.2–4 But much of
the attention in this field has been focused on developing ferro-
electric and high-dielectric inorganic or inorganic–organic
hybrid compounds such as KH2PO4 (KDP
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