Proton doped polyaniline SPME coating Electrochemical Preparation and extraction performance.docVIP

下载本文档

3
0
约1.39万字
约 13页
2017-05-05 发布于浙江
举报
版权申诉

Proton doped polyaniline SPME coating Electrochemical Preparation and extraction performance.doc

1、本文档共13页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
5、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
6、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
7、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
8、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

Proton doped polyaniline SPME coating Electrochemical Preparation and extraction performance

Proton doped polyaniline SPME coating Electrochemical Preparation and extraction performance OF: Juan Zhao Faqiong DU Wei Bai-Zhao Zeng [Abstract] The effects of proton acid type polymer polyaniline coating on the electrical microstructure and extraction performance. Containing 0.1 ~ 0.2 mol / L aniline H2SO4, HCl, HNO3, HClO4, and H3PO4 solution, by cyclic voltammetry polymerization at the surface of platinum wire proton acid doped polyaniline SPME head. using a scanning electron microscope from the first extraction to characterize the microstructure, the optimum conditions (0.35 g / mL NaCl, 50 ℃ 30 min extraction, the to 7 for the simulation of aromatic compounds, materials, use of gas chromatography to test their extraction performance. The results show that: in HNO3 and HClO4 solution polymerization of the polyaniline coating the porous structure with uniform, smooth surface and high membrane extraction efficiency, suitable for efficient extraction of aromatic compounds. [Keywords:] polyaniline, solid phase micro extraction, proton acids, cyclic voltammetry, gas chromatography Abstract Polyaniline (PANI) coatings were prepared on the surface of platinum wires by cyclic voltammetry in 0.1-0.2 mol / L aniline solutions containing different bronsted acids (H2SO4, HCl, HNO3, HClO4 and H3PO4). The microstructure of resulted fibers was characterized by SEM, and the extraction capability was estimated by gas chromatography using 7 aromatic compounds as models under selected conditions (0.35 g / mL NaCl; extract 30 min under 50 ℃). It was found that PANs prepared in HNO3 and HClO4 solutions exhibited uniform porous structure and their extraction efficiency was higher for all models. PANI fibers with expected extraction capability thus may be fabricated by simply selecting suitable bronsted acid as supporting electrolyte. Keywords Polyaniline; Solid phase microextraction; Bronsted acid; Cyclic voltammetry; Gas charomatography 1 Introduction In 200