Breakdown and Evolution of the Protective Oxide Scales of AISI 304 and AISI 316 Stainless Steels under High-Temperature Oxidation英文文献资料.docVIP

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Breakdown and Evolution of the Protective Oxide Scales of AISI 304 and AISI 316 Stainless Steels under High-Temperature Oxidation英文文献资料.doc

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Breakdown and Evolution of the Protective Oxide Scales of AISI 304 and AISI 316 Stainless Steels under High-Temperature Oxidation英文文献资料

HindawiPublishingCorporation InternationalJournalofCorrosion Volume2011,ArticleID824676,10pages doi:10.1155/2011/824676 ResearchArticle BreakdownandEvolutionoftheProtective OxideScalesofAISI304andAISI316Stainless SteelsunderHigh-TemperatureOxidation K.A.Habib,M.S.Damra,J.J.Saura,I.Cervera,andJ.Bell′es DepartamentodeIngenier′?adeSistemasIndustrialesyDise?no,UniversitatJaumeI,12071Castell′on,Spain CorrespondenceshouldbeaddressedtoK.A.Habib,razzaq@esid.uji.es Received11April2011;Accepted15June2011 AcademicEditor:RavinKumarDayal Copyright?2011K.A.Habibetal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense, whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited. ThefailureoftheprotectiveoxidescalesofAISI304andAISI316stainlesssteelshasbeenstudiedandcomparedat1,000 Cin ? syntheticair.First,theisothermalthermogravimetriccurvesofbothstainlesssteelswereplottedtodeterminethetimeneededto reachthebreakdownpoint.Thedi?erentresistanceofeachstainlesssteelwasinterpretedonthebasisofthenatureofthecrystalline phasesformed,themorphology,andthesurfacestructureaswellasthecross-sectionstructureoftheoxidationproducts.The weight gain of AISI 304 stainless steel was about 8 times greater than that of AISI 316 stainless steel, and AISI 316 stainless steelreachedthebreakdownpointabout40timesmoreslowlythanAISI304stainlesssteel.Inbothstainlesssteels,reaching thebreakdownpointmeantthelossoftheprotectiveoxidescaleofCr2O3,butwhereasinAISI304stainlesssteeltheCr2O3scale totallydisappearedandexclusivelyFe2O3 wasformed,inAISI316stainlesssteelsomeCr2O3 persistedandFe3O4 wasmainly formed,whichmeansthatAISI316stainlesssteelismoreresistanttooxidationafterthebreakdown. 1.Introduction ofstainlesssteelsat1,000 C.Attemperaturesabove800 C, ? ? the evaporation of chromium can occur, and this tends to convert the 50–200μm thick protective scale of Cr2O3 which was formed initially to a