Catalytic Chemical Vapor Deposition Synthesis of Carbon Aerogels of High-Surface Area and Porosity英文文献资料.docVIP
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Catalytic Chemical Vapor Deposition Synthesis of Carbon Aerogels of High-Surface Area and Porosity英文文献资料
HindawiPublishingCorporation
JournalofNanotechnology
Volume2012,ArticleID708626,5pages
doi:10.1155/2012/708626
ResearchArticle
CatalyticChemicalVaporDepositionSynthesisof
CarbonAerogelsofHigh-SurfaceAreaandPorosity
ArmandoPe?na, EdgarCa?nizales, andJoaqu′?nL.Brito
1JulioPuerta,1,2Aim′eGuerrero,3 4 5
1
2
3
4
5
LaboratoriodeF′?sicadePlasmayNanotecnolog′?a,UniversidadSim′onBol′?var,Apartado89000,Caracas1080,Venezuela
DepartamentodeF′?sica,UniversidadSim′onBol′?var,Apartado89000,Caracas1080,Venezuela
DepartamentodeCienciasdelosMateriales,UniversidadSim′onBol′?var,Apartado89000,Caracas1080,Venezuela
PDVSA-Intevep,LosTeques,Apartado76343,Caracas1070-A,Venezuela
CentrodeQu′?mica,InstitutoVenezolanodeInvestigacionesCient′??cas,Apartado20632,Caracas1020,Venezuela
CorrespondenceshouldbeaddressedtoJulioPuerta,jpuerta@usb.ve
Received16March2012;Revised28August2012;Accepted28August2012
AcademicEditor:TanajiP.Gujar
Copyright?2012ArmandoPe?naetal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense,
whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited.
Inthisworkcarbonaerogelsweresynthesizedbycatalyticchemicalvapordepositionmethod(CCVD).Ferrocenewereemployed
asasourcebothofcatalyticmaterial(Fe)andofcarbon.Gaseoushydrogenandargonwereusedasreductantandcarriergas,
respectively.Theproductsofreactionwerecollectedoveralumina.Themorphologyandtexturalpropertiesofthesootproducedin
thereactionchamberwereinvestigatedusingScanningElectronMicroscopy,High-ResolutionTransmissionElectronMicroscopy,
X-rayphotoelectronspectroscopy,andN2physisorption(BETandBHJmethods).Aftertheevaluationoftheporousstructureof
partialoxidationofcarbonnanostructureswererevealedand0.55by±XPS.0.02cm
3
/gofVBJHwerefound.Thepresenceofironcarbideandthe
2
/gofSBET
1.Introduction
resorcinol-formaldehyde) using sol-gel methods and pro-
cessingtheresultingmaterialundersupercriticalcondi
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