Fe 2＋（EDTA）-NO还原菌的固定化条件优化及还原性能.pdfVIP

学兔兔 化 工 进 展 2009年第28卷第5期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·869· Fe2+(EDTA)．NO还原菌的固定化条件优化及还原性能 荆国华，孙 亮，周作明，郑 娜 (华侨大学环境科学与工程系，福建 厦门 361021) 摘 要：采用海藻酸钠包埋驯化得到的优势还原菌，用于还原BioDeNO 工艺中吸收NO后形成的Fe (EDTA)一NO。 最佳包埋条件为：海藻酸钠质量浓度4％，菌体质量浓度200mg／L，CaC12质量浓度2％，包埋时间16h。此条件 下制备的小球还原性能好，但机械强度不高，溶胀破裂现象严重。在此基础上，加入2％活性炭和4％硅藻土改良 小球，并将制备的小球进一步用浓度O．02mol／L己二胺交联60min，得到的小球综合性能良好。与游离微生物相 比，其还原性能、耐高温性和耐酸性也有较大程度提高。 关键词：NOx；固定化微生物；Fe2+(EDTA)一NO；还原菌 中图分类号：X 701 文献标识码：A 文章编号：1000—6613(2009)05—0869—05 Optimizing immobilization of Fe (EDTA)．NO reducing microorganisms and their reduction performance JINGGuohua，SUNLiang，ZHOUZuoming，ZHENGNa (DepartmentofEnvironmentalScience andEngineering，HuaqiaoUniversity，Xiamen 361021，Fujian，China) Abstract：The optimum immobilization condition and the performance of the imm obilized beads in reducing Fe (EDTA1一NO was investigated．The beads embedded for 1 6 h with 4％ SOdium alginate， 200 mg／L microorganisms and 2％ calcium chloride had good performance in reduction ability． However，they had a low mechanical sWength，and were easy to be ruptured and swelled．The mechanical properties of the immobilized beads were improved greatly by first adding 2％ activated carbon and 4％ diatomite into sodium alginate to embed the microorganisms，and then crosslinking the beads with 0．02moI／L hexanediamine for 60min．In comparison with free bacteria，the immobilized bacteria had a large improvement in reduction perform ance and resistance to high—temperature and acid． Key WOrds：NO ；immobilized microorganism：Fe (EDTA)一NO；reduction bacteria 络合吸收结合生物还原法是一种全新的烟气脱