MCM-41的制备及其在甲苯碳酸二甲酯烷基化中的催化性能.pdfVIP

学兔兔 化 工 进 展 2010年第29卷第5期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·875· HMCM．22／MCM．41的制备及其在甲苯碳酸二甲酯烷基化 中的催化性能 李永昕，吴润泽，薛 冰 (江苏工业学院化学化工学院，江苏 常州 213164) 摘 要：以自制的 HMCM一22作为原料，与中孔分子筛 MCM一41的凝胶在水热条件下进行组装得到 HMCM一22／MCM一41中微孔复合分子筛，采用XRD、N2吸附一脱附及NH3一TPD等方法对合成样品进行表征。结 果表明，合成的样品同时具有中孔分子筛MCM一41与微孔分子筛HMCM一22的特点。采用固定床微型连续流反 应器对HMCM一22／MCM一41复合分子筛催化甲苯与碳酸二甲酯(DMC)的烷基化反应性能进行了评价，考察了 反应温度、甲苯与DMC摩尔配比及空速对烷基化反应的影响。实验发现，HMCM一22／MCM．41催化甲苯DMC 烷基化反应的产物中，对二甲苯的选择性远高于间位和邻位异构体的选择性，表现出良好的催化活性和选择性。 关键词：HMCM一22／MCM一41复合分子筛；甲苯；碳酸二甲酯；对二甲苯 中图分类号：TQ 032．4 文献标识码：A 文章编号：1000—6613(2010)05—0875—05 Synthesis of HMCM--22／MCM--4 1 and catalytic performance for toluene alkylation with dimethyl carbonate LI Yongxin， Runze，XUEBing (Department of Chemical Engineering，Jiangsu Polytechnic University，Changzhou 213164，Jiangsu，China) Abstract：HMCM一22／MCM一4 1 composite molecular sieves with mesoporous and microporous structure were prepared under hydrothermal conditions from HMCM-22．Physicochemical properties of the as—synthesized catalysts were characterized by XRD，N2 adsorption—desorption and NH3一TPD． Results showed the existence of well—structured microphase MCM一22 zeolite and mesophase MCM一4 1 in the composite materials．Selective alkylation of toluene with dimethyl carbonate(DMC)was carried out over HMCM一22／MCM．4 1 composite molecular sieves in a fixed．bed flOW reactor．Effects of reaction conditions on the alkylation of toluene wim DMC were investigated．The selectivity to P．xylene was higher than m—and