弱酸性介质中钙离子与CO2反应制备碳酸钙.pdfVIP

维普资讯 学兔兔 化 工 进 展 2008年第27卷第6期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 弱酸性介质中钙离子与CO2反应制备碳酸钙 熊 辉，莫婉玲，胡江林，梅付名，李光兴 (华中科技大学化学与化工系，材料化学与服役失效湖北省重点实验室，湖北 武汉 430074) 摘 要：研究了弱酸性介质中钙离子与CO2反应生成沉淀碳酸钙的工艺过程，探讨了乙酸钙浓度、反应温度、CO2 压力、反应时间及陈化时间等因素对制备碳酸钙的影响。结果表明，在乙酸钙质量分数17％，CO2分压2．5MPa， 反应温度95℃时，反应3O min，陈化5 h的条件下，碳酸钙的收率为20．6％，制备出分散性良好的平均粒径为 1．4／am的沉淀碳酸钙。 关键词：碳酸钙；碳酸化反应；乙酸钙；CO2 中图分类号：TQ 132．32；O 064 文献标识码：A 文章编号：1000—6613(2008)06—0937—04 Preparation of calcium carbonate by carbonation of calcium ion and COs in weak．acid medium XIONG Hui，MO Wanling，HUJianglin，MEIFuming，LI Guangxing rHubei Key Laboratory of Materials ChemistryService Failure，Department of Chemistry and Chemical Engineering Huazhong University of Science and Technology，Wuhan 430074，Hubei，China) Abstract．-The preparation process ofcalcium carbonate by carbonation ofCO2 and calcium ion in weak-acid medium was studied．The affecting factors such as concentration ofcalcium acetate，pressure ofCO2，reaction temperature，time of aging and reaction time on the preparation of precipitated calcium carbonate were discussed．The optimum reaction conditions were as follows：concentration ofcalcium acetate 1 7％，carbon dioxide pressure 2．5 MPa，reaction temperature 95℃，reaction time 30 minutes，and ageing time 5 hours．The yield of calcium carbonate was about 20．6％．The calcium carbonate particles had good dispersivity and the volumetric mean size was about 1．4 gm．This process provides the basic experiment