油茶壳残渣制备活性炭的工艺.pdfVIP

学兔兔 化 工 进 展 ·4280· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2015年第34卷第12期 油茶壳残渣制备活性炭的工艺 熊道陵，许光辉，张团结，陈金洲，陈超 (江西理工大学冶金与化学工程学院，江西 赣卅【341000) 摘要：以油茶壳醇浸取后残渣为原料，以磷酸活化法制备活性炭，考察了浸渍比、磷酸质量分数和活化温度等 对活性炭吸附性能及其得率的影响；活性炭的吸附性能由碘吸附值、亚甲基蓝吸附值表征。结果表明，在酸／炭 浸渍比为3：1、磷酸质量分数 70％、活化温度 500℃时，活性炭的吸附性能最佳，其碘、亚甲基蓝吸附值和得 率分别为1043．29mg／g、148．5mg／g和38．77％。采用物理吸附仪在77K下测定其N2吸附脱附等温线，利用BET 法和BJH法计算比表面积和孔径分布，其比表面积为1626．45m0儋，平均孔径为4．7nm，总孔容为1．94cm 同 时采用FTIR和XRD分析了活性炭的表面官能团和微观结构。 关键词：活性炭；油茶壳残渣；活化；吸附；制备；孔结构 中图分类号：TQ424．1 文献标志码：A 文章编号：1000—6613(2015)12—4280—05 DoI：10．16085~．issn．1000—6613．2015．12．023 Activated carbon prepared from camellia oleifera shell residue after alcoholextraction XIONG Daoling，XU Guanghui，ZHANG Tuanjie，CHENJinzhou，CHEN Chao (School ofMetallurgy and Chemical Engineering，Jiangxi University ofScienceTechnology，Ganzhou 341000， Jiangxi，China) Abstract：Activated carbons were prepared from camellia oleifera shell residue after alcohoI extraction by phosphoric acid．The influences of impregnation ratio，mass fraction of phosphoric acid and activation temperature on the yield of activated carbon and the adsorption capacity were characterized by adsorption iodine value and adsorption methylene blue value，respectively~The results showed that activated carbon with the optimal adsorption capacity could be prepared at an impregnation ratio of acid／carbon of 3，a phos