电泳膜接触器研究进展.pdfVIP

学兔兔 化 工 进 展 2013年第32卷第 l2期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·2819· 电泳膜接触器研究进展 邹文娴，卢会霞，王建友 (南开大学环境科学与工程学院，天津 300071) 摘 要：电泳膜接触器 (EMC)是在传统电渗析器中引入多孔膜，或用多孔膜代替部分离子交换膜的一种新型 膜分离技术，其中多孔膜作为两液流的接触界面，提供传质的场所，垂直于液流方向的电场是唯一的驱动力。 本文介绍了EMC的工作原理，并简要概述了EMC的膜堆构型及运行模式。详细分析了进料液pH值、电场强 度等操作参数、多孔膜的材质和截留相对分子质量等对EMC过程传质的影响，且对EMC运行过程中多孔膜的 污染状况进行了探讨，并展望了EMC在生物大分子分离和纯化中的应用潜力。EMC中多孔膜的引入，使得EMC 可以用于相对分子质量大于500 Da的生物分子的分离与纯化，进一步拓宽了电渗析的应用领域，而外加电场的 作用能够有效减轻多孔膜的污染，因此，EMC在生物分子的分离与纯化方面具有广阔的应用前景。 关键词：电泳膜接触器；电渗析；超滤膜 中图分类号：TQ 028．8；X 703 文献标志码：A 文章编号：l000—6613(2013)12—2819—08 Doh 10．3969~．issn．1000—6613．2013．12．005 Research progress in study of electrOph0retic membrane contactor ZOUWenxian，LUHuixia，WANGJianyou (School ofEnvironmental Science andEngineering，NankaiUniversity，Tianjin 300071，China) Abstract：The electrophoretic membrane contactor(EMC)is a novel membrane separation technology in which porous membranes are stacked or replaced partial ion exchange membranes by porous membranes in conventional electrodialysis cel1．The porous membranes act as the contact interface between the two liquid streams where the mass transfer takes place．The voltage，applied in a direction perpendicular to the flows，is the only driving force．This review paper described the principles of EMC Cell configuration and operation mode of EMC were briefly discussed．The influences of important operation factors，such as pH of solution and electric field strength，polymer materials and molecular weight cutoff of porous membranes on the mass transfer of EMC process were ana