Reticulation of Aqueous Polyurethane Systems Controlled by DSC Method 英文参考文献.docVIP

Sensors 2006, 6, 536-545 sensors ISSN 1424-8220 ? 2006 by MDPI /sensors Reticulation of Aqueous Polyurethane Systems Controlled by DSC Method Suzana Cakic 1, Caslav Lacnjevac 2,*, Milos B. Rajkovic 2, Ljiljana Raskovic 1 and Jakov Stamenkovic 1 1 Faculty of Chemical Engineering, 16000 Leskovac, Bul. oslobodjenja 124, Serbia Suzana Cakic, e-mail: suzana_cakic@, Ljiljana Raskovic, e-mail: duda@ 2 Faculty of Agriculture, 11080 Belgrade-Zemun, St. Nemanjina 6, Serbia Caslav Lacnjevac, e-mail: ukilaki@eunet.yu, Milos B. Rajkovic, e-mail: rajmi@agrifaculty.bg.ac.yu *Author to whom correspondence should be addressed. E-mail: lcaja@agrifaculty.bg.ac.yu or ukilaki@eunet.yu Received: 31 March 2006; in revised form: 28 April 2006 / Accepted: 14 May 2006 / Published: 2 June 2006 Abstract: The DSC method has been employed to monitor the kinetics of reticulation of aqueous polyurethane systems without catalysts, and with the commercial catalyst of zirconium (CAT?XC-6212) and the highly selective manganese catalyst, the complex Mn(III)- diacetylacetonemaleinate (MAM). Among the polyol components, the acrylic emulsions were used for reticulation in this research, and as suitable reticulation agents the water emulsible aliphatic polyisocyanates based on hexamethylendoisocyanate with the different contents of NCO-groups were employed. On the basis of DSC analysis, applying the methods of Kissinger, Freeman-Carroll and Crane-Ellerstein the pseudo kinetic parameters of the reticulation reaction of aqueous systems were determined. The temperature of the examination ranged from 50oC to 450oC with the heat rate of 0.5oC/min. The reduction of the activation energy and the increase of the standard deviation indicate the catalytic action of the selective catalysts of zirconium and manganese. The impact of the catalysts on the reduction of the activation energy is the strongest when using the catalysts of manganese and