Schiffs Bases and Crown Ethers as Supramolecular Sensing Materials in the Construction of Potentiometric Membrane Sensors 英文参考文献.docVIP

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Schiffs Bases and Crown Ethers as Supramolecular Sensing Materials in the Construction of Potentiometric Membrane Sensors 英文参考文献.doc

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Schiffs Bases and Crown Ethers as Supramolecular Sensing Materials in the Construction of Potentiometric Membrane Sensors 英文参考文献

Sensors 2008, 8, 1645-1703 sensors ISSN 1424-8220 ? 2008 by MDPI /sensors Review Schiffs Bases and Crown Ethers as Supramolecular Sensing Materials in the Construction of Potentiometric Membrane Sensors Farnoush Faridbod 1, Mohammad Reza Ganjali 1,*, Rassoul Dinarvand 2, Parviz Norouzi 1 and Siavash Riahi 3 1 Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran 2 Medical Nanotechnology Research Centre, Medical Sciences/University of Tehran, Tehran, P.O. Box 14155-6451, Iran 3 Institute of Petroleum Engineering, Faculty of Engineering, University of Tehran, Tehran, P.O. Box 14155-6455, Iran * Author to whom correspondence should be addressed; E-mail: ganjali@khayam.ut.ac.ir Received: 31 December 2007 / Accepted: 22 February 2008 / Published: 11 March 2008 Abstract: Ionophore incorporated PVC membrane sensors are well-established analytical tools routinely used for the selective and direct measurement of a wide variety of different ions in complex biological and environmental samples. Potentiometric sensors have some outstanding advantages including simple design and operation, wide linear dynamic range, relatively fast response and rational selectivity. The vital component of such plasticized PVC members is the ionophore involved, defining the selectivity of the electrodes complex formation. Molecular recognition causes the formation of many different supramolecules. Different types of supramolecules, like calixarenes, cyclodextrins and podands, have been used as a sensing material in the construction of ion selective sensors. Schiffs bases and crown ethers, which feature prominently in supramolecular chemistry, can be used as sensing materials in the construction of potentiometric ion selective electrodes. Up to now, more than 200 potentiometric membrane sensors for cations and anions based on Schiffs bases and crown ethers have been reporte