Trans-dichloro-2,3-naphthalenediamine bis[(2-methoxyethyl)-(diphenyl)phosphine]-ruthenium(II) Complex 英文参考文献.docVIP

Molbank 2010, M696; doi:10.3390/M696 OPEN ACCESS molbank ISSN 1422-8599 /journal/molbank Short Note Trans-dichloro-2,3-naphthalenediamine bis[(2-methoxyethyl)- (diphenyl)phosphine]ruthenium(II) Complex Ismail Warad Department of Chemistry, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi Arabia; E-Mail: warad@.sa; Tel./Fax: +96-61-4675992 Received: 21 July 2010 / Accepted: 10 September 2010 / Published: 17 September 2010 Abstract: Trans-dichloro-2,3-naphthalenediamine bis[(2-methoxyethyl)(diphenyl)phos- phine]ruthenium(II) complex Cl2Ru(?1-Ph2PCH2CH2OCH3)2(C10H10N2) has been obtained by reaction of equimolar amounts of Cl2Ru(P?O)2 complex 2 with one equivalent of 2,3- naphthalenediamine as co-ligand in very good yield. The structure of this new complex 3 was confirmed by elemental analysis, IR, 31P-NMR 1H-NMR, 13C-NMR, UV-visible spectroscopy and FAB-MS. Keywords: ruthenium(II) complexes; Hemilabile ether-phosphine; diamine ligand 1. Introduction Bifunctional ether-phosphines (O,P) have significantly affected the isolation of coordinatively unsaturated species [1-7]. These ligands are provided with oxygen atoms incorporated in open-chain ether moieties which form a weak metal-oxygen contact while the phosphorus atom is strongly coordinated to the metal [3-9]. In these “hemilabile“ ligands, the ether moiety is regarded as an intramolecular solvent molecule stabilizing the vacant coordination site by chelation. Phosphorus– oxygen hemilabile ligands like 2-(diphenylphosphino)ethyl methyl ether (P~O), reacts with various metals of catalytic relevance due to their ability to act as both a chelate ligand, stabilizing the metal complex, and a monodentate ligand providing a free coordination site for an incoming substrate (through the labilization of the weakly bonded oxygen atom) [1-10]. 2. Result and Discussion The Ph2PCH2CH2OCH3 ligand and comp