Upgrading of Wastewater Treatment Plants Through the Use of Unconventional Treatment Technologies Removal of Lidocaine, Tramadol, Venlafaxine and Their Metabolites 英文参考文献.docVIP
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Upgrading of Wastewater Treatment Plants Through the Use of Unconventional Treatment Technologies Removal of Lidocaine, Tramadol, Venlafaxine and Their Metabolites 英文参考文献
Water 2012, 4, 650-669; doi:10.3390/w4030650
OPEN ACCESS
water
ISSN 2073-4441
/journal/water
Article
Upgrading of Wastewater Treatment Plants Through the Use of
Unconventional Treatment Technologies: Removal of Lidocaine,
Tramadol, Venlafaxine and Their Metabolites
Paola C. Rúa-Gómez 1,*, Arlen A. Guedez 1, Conchi O. Ania 2 and Wilhelm Püttmann 1
1
Institute of Atmospheric and Environmental Sciences, Department of Environmental Analytical
Chemistry, J.W. Goethe University Frankfurt am Main, Altenh?ferallee 1, Frankfurt am Main 60438,
Germany; E-Mails: arlenaguedez@ (A.A.G.); puettmann@iau.uni-frankfurt.de (W.P.)
2
Instituto Nacional del Carbon (INCAR-CSIC), Apartado 73, Oviedo 33080, Spain;
E-Mail: conchi.ania@incar.csic.es
* Author to whom correspondence should be addressed; E-Mail: ruagomez@iau.uni-frankfurt.de;
Tel.: +49-69-798-40230; Fax: +49-69-798-40240.
Received: 1 June 2012; in revised form: 15 August 2012 / Accepted: 3 September 2012 /
Published: 11 September 2012
Abstract: The occurrence and removal efficiencies of the pharmaceuticals lidocaine (LDC),
tramadol
(TRA)
and
venlafaxine
(VEN), and
their
major
active
metabolites
monoethylglycinexylidide (MEGX), O-desmethyltramadol (ODT) and O-desmethylvenlafaxine
(ODV) were studied at four wastewater treatment plants (WWTPs) equipped with activated
sludge treatment technologies. In parallel to activated sludge treatment, the removal
efficiency of the compounds in pilot- and full-scale projects installed at the WWTPs was
investigated. Within these projects two different treatment methods were tested: adsorption
onto powdered/granulated activated carbon (PAC/GAC) and ozonation. The metabolite
MEGX was not detected in any sample. The concentrations of the target analytes in
wastewater effluents resulting from activated sludge treatment ranged from 55 to 183 (LDC),
88 to 416 (TRA), 50 to 245 (ODT), 22 to 176 (VEN) and 77 to 520 ng L?1 (ODV). In th
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