PEK-C增韧环氧树脂的研究Ⅱ.pdfVIP

化学与黯合 . 427 . CHEMISTRY AND ADHESION 2016 茸第38 卷第6 期 PEK-C 增韧环氧树脂的研究II* 冯浩l ，曲春艳2，王德、志 2 ，毛勇气王海民2 ，王文博 1 ，王东旭 1 ( 1 黑龙江省科学院石油化学研究院，黑龙江哈尔滨 15翩。:2黑龙江省科学院高技术研究院，黑龙江哈尔滨 15∞20) 摘要:采用盼歌基聚芳酶酣为增韧剂改性环氧树脂，以芳香胶为固化剂，制备出一种改性环氧树脂。研究了改性树脂的耐 热性和微观结构。实验结果表明:随着盼歌基聚芳隧嗣用量的增加，改性树脂的玻璃化转变温度先增高后降低，当盼歌基聚芳 酷圈用量为 15phr 时，改性树脂的玻璃化转变温度最高，达到 193C。同时，改性树脂的微观结构随着PEK-C 用量增加而发生 变化。由海岛结构先转变成双连续互锁结构，最终发生相反转。 关键询:盼歌基聚芳隧嗣;环氧树脂;增韧;耐热性;相态 中图分类号:TQ 323 .5 文献标识码:A 文章编号:1∞1-0017(2016)06-0427斗4 A Study 00 由e Epoxy Adhesive Modified wi伽 Poly(Aryl Ether Ketooe) D 2 阳NG Hao, QU Chun-yan飞 WANCD←z.hj飞 MAO Yoni, WANG Hai-min , WANG Wen-bo and WANG D。晗旷 (l./n.sti.t脚ofPetro chemis町• HeiJo咱归啄Academr of Sciences, Harbin 15ω矶 China; 2./n.st山le ofAdvanced Technology, HeiJo哺归啄Academr of.衍iences， Harbin 15ω120， China) Abstract: A modified epo巧W幽 prepared. 四e epoxy w副 modified by poly ether ketone-cadro (PEK-C) 幽 toughener and aromatic amine 描 curing agent. 币le heat resistance and microstructure of the modified resin were studied. The result showed 由at the gl础衍回sition temμrature of the modified resin incre脱d firsùy and then decreased with the increa拇 of the dωage of PEK - C. When the PEK -C content was 15phr, the gl幽S transition temperature w国 193t: which w皑白ehigh倒. And the microstructure of the modified resin wo叫d change with the incre耐。f the amount of PEK-C. 四e pha盹 S田cture ∞merted from sea-island s国cture to dOl.必le continuous interl创king structure, and finally the pha蹄 inversion 阴阳时. Key words: Poly (町1 e出er ketone); epoxy adh咄咄tωghening; heat resistance; ph翩翩le 1.1 主要原材料 前言