铁吸收和解吸氢、筑、氟的动力学同位素效应.PDF

CNIC-01931 CAEP-0209 铁吸收和解吸氢、筑、氟的动力学同位素效应 黄刚曹小华龙兴贵 (中国工程物理研究院核物理与化学研究所，绵阳，621900) 摘要 应用反应速率分析方法，测定了恒容体系中钦在 550 r--..; 750 OC 吸 收氢、氛和氛的户-t 曲线以及氢(筑、氮)化钦在 350r--..; 550 OC 热解吸 的 ρ-t 曲线，得到钦吸氢、氛和焦的表观活化能分别为 (55. 6 士2.4) 1 1 1 kJ • mo1- , (110.2+ 3. 0) kJ • mo1- 和(155. 5 士3. 2) kJ • mo1- ，氢 (氛、焦)化钦热解吸的表观活化能分别为 (27. 1 士O. 4) kJ • m0 1--1 , 1 (42. 3 士 1.9) kJ • mo1- 和 (62.1 士1. 6) kJ • mo1-1 o 钦吸焦的表观 活化能最高，表明钦氟化反应更难于进行。氟化钦热解吸的表观活 化能也比氢化铁高，表明氟化钦在相同条件下比氛化铁和氢化钦更 稳定 活化能数据显示，在吸收和解吸气体过程中均存在显著的动 o 力学氢同位素效应 o 关键词:铁表观活化能 同位素效应 38 The Kinetic Isotope Effect of Hydrogen Deuterium and Tritium Absorbed and Desorbed by Titanium (In Chinese) HUANG Gang CAO Xiaohua LONG Xinggui (Institute of Nuclear Physics and Chemistry , CAEP，孔1ianyang ， 621900) ABSTRACT ρ-t curves of hydrogen , deuterium and tritium absorption at 550-750 oc and desorption at 350- 550 oC by titanium were investigated. The rate con- stants of absorption and desorption for hydrogen , deuterim and tritium on each temperature are determined and the activation energy values obtained by this analysis are (55. 6 士2.4) kJ. mol- 1 , (110.2+3.0) kJ. mol- 1 and (155.5 士 3.2) kJ • mol- 1 for absorption and (27.1 土 0.4) kJ • mol- 1 , (42.3 士1. 9) kJ • mol- 1 and (62.1 士1. 6) kJ • mol- 1 for desorption respectively. The activa- tion energy value of tritium absorption is highest which shows tit