镀铌不锈钢双极板的电化学性能-中国腐蚀与防护学报.PDF

第33 卷 第2 期 中国腐蚀与防护学报 Vol. 33 No. 2 2013 年4 月 Journal of Chinese Society for Corrosion and Protection Apr. 2013 镀铌不锈钢双极板的电化学性能 曹彩红 梁成浩 黄乃宝 大连海事大学交通运输装备与海洋工程学院 大连 116026 摘要: 采用对水和空气稳定的氯化胆碱:乙二醇= 1:2 （摩尔比）的离子液体为电解质，在316 不锈钢基体上进行 电镀铌，考察模拟质子交换膜燃料电池（PEMFC ）环境中镀铌不锈钢双极板的电化学性能。结果表明，以氯化 胆碱类离子液体为电解质在316 不锈钢表面可获得平整均匀的颗粒状铌镀层。在模拟质子交换膜燃料电池环 境中，镀铌316 不锈钢的腐蚀电位得到提高，维钝电流密度减小，阳极极化性能得到改善；孔蚀电位正移，反应 电阻增大，耐蚀性能提高。能谱和X 射线衍射分析结果表明，镀铌后316 不锈钢表面生成化学惰性良好的NbO 和Nb O ，形成耐蚀“屏障”，改善了不锈钢表面膜的钝化能力，提高了不锈钢的电化学稳定性能。 2 5 关键词: 氯化胆碱离子液体 铌 不锈钢双极板 电化学性能 中图分类号：TG 174.4 文献标识码：A 文章编号：1005-4537(2013)02-0123-06 Electrochemical Characteristic of Stainless Steel Bipolar Plates Deposited with Niobium CAO Caihong , LIANG Chenghao , HUANG Naibao Transportation and Logistics Engineering College , Dalian Maritime University , Dalian 116026, China Abstract: Niobium was electrodeposited on 316 stainless steel in water and air- stable choline chloride based ionic liquid (choline chloride: ethylene glycol=1:2 （mole ratio)). The electrochemical characteristic of the coated steel was investigated in simulated proton exchange membrane fuel cell (PEMFC) environment. The results indicated that the uniform film was obtained on stainless steel surface. In simulated PEMFC environment, after 316 stainless steel was coated with niobium, its electrochemical characteristics were improved greatly, such as the corrosion potential increased, the passivation current density decreased, the pitting potential moved toward positive, and the reaction resistance inc