增韧剂及成核剂对PP–R复合材料性能的影响.pdf

第45 卷，第4 期 工 程 塑 料 应 用 Vol.45 ，No.4 108 2017 年4 月 ENGINEERING PLASTICS APPLICATION Apr. 2017 doi:10.3969/j.issn.1001-3539.2017.04.023 增韧剂及成核剂对PP–R 复合材料性能的影响* 代前飞，尹晓刚，崔奥然，付海，班大明，龚维 ( 贵州师范大学材料与建筑工程学院，贵阳 550025) 摘要：采用注射成型法制备无规共聚聚丙烯(PP–R) 复合材料，结合差示扫描量热仪、扫描电子显微镜、X 射线衍 射仪及偏光显微镜等技术，分析了乙烯– 辛烯共聚物+ 高密度聚乙烯增韧剂及WBG Ⅱ型 成核剂对PP–R 复合材β 料力学性能和结晶行为的影响。结果表明，增韧剂与成核剂对复合材料的综合性能有明显的影响， 成核剂和增韧β 剂同时加入到PP–R 材料中，协效提高了复合材料的冲击强度，为78.7 kJ ／m2 ，与纯PP–R 材料比较提高了175% ，而 α β 细化，进而改善其冲击韧性。 对拉伸及弯曲强度影响较小。同时，加入增韧剂及成核剂均能诱导 晶向 晶转变，晶粒 关键词：无规共聚聚丙烯；增韧剂；结晶行为；成核剂；力学性能β 中图分类号：TQ325.1+4 文献标识码：A 文章编号：1001-3539(2017)04-0108-05 Effects of Toughening Agent and Nucleating Agent on Properties of PP–R Composites Dai Qianfei ，Yin Xiaogang ，Cui Aoran ，Fu Hai ，Ban Daming ，Gong Wei (College of Materials and Architectural Engineering ，Guizhou Normal University ，Guiyang 550025 ，China) Abstract ：PP–R composites were prepared by inj ection molding method. The effects of toughening agent (POE+PE–HD) and β nucleating agent (WBG Ⅱ) on the mechanical properties and crystallization behavior of PP–R composites were analyzed by DSC ，SEM ，XRD and POM techniques. The results show that the toughening agent and the nucleating agent have obvious effect on the comprehensive properties of the PP–R composites. When β nucleating agent and toughening agent are added into the PP–R material at the same time ，the impact strength of the 2 PP–R composites is 78.7 kJ ／m ，which is 175% higher than that of pure PP–R ，and the tensile and flexural strength has little effect. The addition of toughening agent and nucleating agent can induce the transformati