石蜡制备高碳醇工艺条件研究.pdfVIP

45 卷 12 期 当 代 化 工 Vol.45，No.12 2016 年12 月 Contemporary Chemical Industry December，2016 石蜡制备高碳醇工艺条件研究 孙 威，龙小柱，李 乐 （沈阳化工大学 化学工程学院，辽宁 沈阳 110142 ） 摘 要：以石蜡为原料，硼酸酐为催化剂，经催化氧化、水洗、水解、萃取制备高碳醇。研究发现在催化剂 用量为6% （基于石蜡质量，下同），氧化时间为4 h ，氧化温度为190 ℃，NaOH 质量分数为4% ，水解温度为85 ℃， 水解时间为3 h 为最佳的工艺条件，产率最高。利用FTIR 分析产物的结构，结果表明，制备产物的官能团与目标 产物一致。对该工艺条件下合成的产物进行测定，酸值为0.34 ，产率为20.12%，高于其他工艺条件。 关 键 词：石蜡；催化氧化；萃取；高碳醇 中图分类号：TQ 644 文献标识码： A 文章编号： 1671-0460 2016 ）12-2797-04 Study on Process Conditions for Preparation of Higher Alcohols From Paraffin S UN Wei LON G Xiao-zhu LI Le （College of Chemical Engineering ,Shenyang University of Chemical Technology, Liaoning Shenyang 110142, China ） Abstract: Using paraffin as raw material and boric anhydride as catalyst, high carbon alcohol was prepared by catalytic oxidation, washing, hydrolysis and extraction. The optimum reaction conditions were determined as follows: catalyst quantity 6% (based on the mass of paraffin, the same below), the oxidation time 4 h, the oxidation temperature 190 ℃, NaOH mass fraction 4%,the hydrolysis temperature 85 ℃, the hydrolysis time 3 h.FTIR analysis showed that the functional groups of the prepared products were consistent with the target products. The products synthesized under the optimum conditions were determined, The acid number was 0.34 and the yield was 20.12%, higher than other process conditions. Key words: paraffin; catalytic oxidation; extraction; higher alcohol [1] 热恒温干燥箱，NEXUS-470 傅立叶变换红外光谱仪 高碳醇又称高级脂肪醇或高级烷醇 。高碳醇 及其衍生物在众多领域被广泛应用，如化工、石油、 均为标准测试装置。 [2,3] 食品、皮