应用石油中“三芴”系列判识沉积环境几个问题.pdf

Advances in Geosciences 地球科学前沿, 2013, 3, 22-28 doi:10.12677/ag.2013.31004 Published Online February 2013 (/journal/ag.html) Several Problems on the Use of Relative Abundances of Fluorenes, Dibenzofurans and Dibenzothiophenes in the Study * of Depositional Environment # Meijun Li , Shengbao Shi, Tieguan Wang, Liwen Zhang, Fulin Yang State Key Laboratory of Petroleum Resources and Prospecting, College of Geosciences, China University of Petroleum, Beijing Email: #meijunli2008@, meijunli@ Received: Aug. 2nd th th , 2012; revised: Sep. 24 , 2012; accepted: Oct. 6 , 2012 Abstract: The relative abundances of fluorene (F), dibenzofuran (DBF) and dibenzothiophene (DBT) and their methyl substituted homologues in oils and sedimentary organic matters are important geochemical parameters indicating the depositional environments. This paper discusses the relative contents of Fs, DBFs and DBTs using three different methods, i.e. only considering parent molecules, including methyl- and dimethyl-homologues, respectively. It suggested that the relative abundances of fluorenes keep an approximately constant value in oils originated from both typical oxic terrestrial lacustrine shales and anoxic marine carbonate source rocks. In comparison, the relative abundance of DBFs is relatively higher when methyl- and dimethyl-dibenzofurans were considered. Correspondingly, the relative abundances of DBTs decrease by a maximum of 15%. The paper preliminarily analyzes the chemical mechanism that results in these differences between Fs, DBFs and DBTs. It is concluded that it is better to consider more