有机硼羟丙基胍胶压裂液交联动力学研究.pdf

Journal of Advances in Physical Chemistry 物理化学进展, 2017, 6(1), 37-43 Published Online February 2017 in Hans. /journal/japc /10.12677/japc.2017.61005 Study on Reaction Dynamics of Organic Boric Cross-Linker and Hydroxypropyl Guar Gum 1* 1 1 2 Ping Tang , Xing Lin , Chenggang Zheng , Kuo Shi 1 Petroleum Exploration and Production Research Institute, Sinopec, Beijing 2 China National Offshore Oil Corporation DATONG SNG Project, Datong Shanxi th rd th Received: Feb. 7 , 2017; accepted: Feb. 23 , 2017; published: Feb. 28 , 2017 Abstract Based on cross linking reaction of organic boric cross-linker and hydroxypropyl guar gum, central composite experimental design is used to construct a mathematic model of guar gel viscosity with the key factors. Six key factors, including the organic boron activation energy (Ea), temperature (T), pH value, organic boric cross-linker, concentration, hydroxypropyl guanidine gum concentration, and time (t), were chosen for the study. The model could thereafter contribute to the development of organic boric cross-linker, construction of fracturing system, prediction and evaluation of the fracturing fluid; it also has important practical significance for the optimization of fracturing execution conditions. Keywords Organic Boric Cross-Linker, Hydroxypropyl Guar Gum, Fracturing Fluid, Cross Linkage Dynamics 有机硼羟丙基胍胶压裂液的交联动力学研究 1* 1 1 2 唐 萍 ，林 鑫 ，郑承纲 ，石 阔 1 中国石化石油勘探开发研究院，北京 2 中国海洋石油总公司大同煤制气项目筹备组，山西 大同 收稿日期：2017年2月7 日；录用日期：2017年2月23 日；发布日期：2017年2月28 日 摘 要 本文以有机硼交联剂和羟丙基胍胶的交联反应为基础，选择了影响该反应过程的六个主控因素——有机