规整填料型加氢脱硫催化剂的制备及性能评价.pdfVIP

维普资讯 学兔兔 化 工 进 展 ·1090· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2008年第27卷第7期 规整填料型加氢脱硫催化剂的制备及性能评价 张立佳，杨红健，侯凯湖 (河北工业大学化工学院，天津 300130) 摘 要：用电化学方法制备多孔氧化铝膜，并负载Mo．Co活性组分制得了金属支撑一多孔层规整填料型加氢催化 剂。采用BET和SEM技术表征了多孔性氧化铝膜的物理结构，并考察了电解及后处理条件的影响。结果表明， 电解液浓度、氧化时间、水封时间、水封温度等对多孔氧化铝膜的比表面积影响显著。采用二次氧化的方法，在 质量分数为4％的草酸电解液、氧化时间1 h、80℃水封3 h条件下，所制备的多孔氧化铝膜具有相对较大的比表 面积。汽油重馏分加氢反应结果表明该类催化剂具有较高的催化活性和选择性。 关键词：阳极氧化；多孔氧化铝；规整填料；催化剂；加氢脱硫 中图分类号：0 643．38 文献标识码：A 文章编号：1000—6613(2008)07—1090一O6 Preparation and evaluation of hydrodesulfurization catalysts supported on regular filler-type porous anodic alumina ZHANGLijia，YANG Hongfian，HOUKaihu (School ofChemical Engineering，Hebei University ofTechnology，Tianjin 300130，China) Abstract：Catalyst suppo~s with a metal wall and a porous layer，were prepared by an anodic oxidation method．The supposed Co—Mo／A1203一A1 catalysts were obtained by impregnation with ammonium molybdate and cobalt nitrate．The physical structure of the porous anodic alumina was characterized by using SEM and BET．The results indicated that the influences of electrolysis and after-treatment conditions，including electrolyte concentration，hydration time and temperature，and organic addition， on the structure of porous anodic alumina were significant．The pore size and SREr can be adjusted by altering the electrolysis and after treatment conditions．High—porosity and higher surface area alumina suppo~