铁阳极电凝聚处理活性黑KN-B染料废水动力学分析.pdfVIP

吃刻可岛.4#.. 第 31 卷第1 期 Vol. 31 NO.l 2008 年 1 月 ~nvironmental Science Technology Jan:. 2008 铁阳极电凝聚处理活性黑KN-B 染料废水动力学分析 梁吉艳M， 杨蕴哲阳， 胡夜敏1 (I东北大学资源环境与土木工程学院，辽宁沈阳 1∞04; 2.忧阳工业大学理学院，辽宁沈阳 11∞24) 摘 要:采用铁为阳极的原位电凝聚方法处理活性黑KN-B 染料废水。以活性黑 KN-B 在特征吸收波长制m和255nm 的吸光度 变化为分析指标，考察了电流密度、染料溶液初始pH 值、电介质浓度及种类、温度、染料浓度等影响因素对染料废水脱色过程及脱色速 率常数的影响。同时根据化学反应动力学理论对其脱色的动力学过程及脱色机理进行了初步探讨与分析。实验结果表明:染料溶液的脱 色反应符合一级反应动力学过程;电流密度、染料浓度、染料溶液初始pH 值及电解质的种类及浓度对一级反应速率常数影响显著，而染 料溶液温度对一级反应速率常数的影响较小;染料废水的脱色过程是电凝聚和染料还原共同作用的过程。 关键词:电凝聚; 活性黑阳-B; 脱色; 动力学分析 中图分类号:X703.1 文献标识码:A 文章编号:1ω，3-6切4(2∞8)01-α削-04 Kinetics Analysis of Reactive Black KN-B Wastewater Treatment by ElectrocoaguIation with a SacrificiaI Iron Anode l 1 LIANG Ji-yan 1.2, Y ANG Yun-zhe .2 , HU Xiao-min (l.Sch∞，1 of Resource Environment and Civil EngineerÎl毡， Northeast University , Shenyang 11∞04， China; 2.Sch∞1 of Science , Shenyang University of Technology , Shenyang 110024， αlÎna) Abs位ac包: Decolorization kinetics and mechanism was studied on treatment of reactive black KN-B simulated wastewater by electrocoagulation(EC) with a sacrificiaI iron anode. The influence of current density , initial pH , s严cies and concentration of electroly旬， initiaI concentration of dye , water temperaωre on 由e decolorization process and reaction constant was investigated. Results showed that the dye removaI was in accordance with the first order reaction. Current density , initiaI concentration of dye , initiaI pH and species of electrolyte had the obvious effect on decolorization _re actio