聚丙烯纤维复合材料界面结晶及力学性能.pdfVIP

摘要 界面剪切促进了界面结晶层分子链的取向，并且剪切越强分子链取向程度越大， 而这些取向的分子链最终导致了界面结晶形态的不同。随着横晶厚度的增加， 界面剪切强度增大，而且界面剪切强度不仅受横晶的影响而且晶型也对其有显 著的影响。对于界面为α 球晶、α 横晶和β 横晶的复合材料试样，界面剪切强度 依次增大，并且含有β 横晶的单纤维复合材料获得的界面剪切强度最大。相对 于无定型结构，横晶结构提高了复合材料的拉伸强度，同时，β 横晶结构比α 横 晶结构对复合材料拉伸强度的促进更加明显，且β 横晶能有效阻止裂纹扩展。 关键词：剪切应力 等规聚丙烯 界面结晶 界面剪切强度 拉伸强度 II 万方数据 Abstract Abstract Fiber reinforced polymer composites have obtained great attentions and widely research because of their comprehensive properties in the past decades. For polymer/fiber composites, except for the intrinsic strength of the matrix and reinforced fiber, interfacial crystallization plays an important role in determining the mechanical properties of composites. Therefore, tunning of the interfacial crystallization provides a promising method to obtain polymer/fiber composites with desirable mechanical properties. For polymer/fiber composites, Transcrystallinity (TC) is regarded as one very important kind of interfacial features, which has obtained more and more attentions. Meanwhile, the influence of the structure of TC on the interfacial shear strength (IFSS) has been widely studied. In our previous studies, interfacial crystallization is tunned in iPP/GF composites by the method of shear-induced crystallization. On the isothermally crystalline conditions, interfacial shear stress indeed has a great influence on