封闭型水性聚氨酯的制备及表征.pdfVIP

Vol.44 No.10 涂料工业 第 44 卷第 10 期 PAINT COATINGS INDUSTRY Oct. 2014 2014 年 10 月 封闭型水性聚氨醋的制备及表征 胡 鹏1 ，贺龙强1 ，刘中阳1 ，何伟国2 (1.焦作大学化工与环境工程学院，河南焦作 454000;2. 黎明化工研究院，河南洛阳 471000) 摘 要:以甲苯二异氨酸醋(TDI) 、聚乙二醇400 ( PEG-400) 为主要原料，合成端异氨酸醋基的聚 氨醋预聚体，以亚硫酸氢纳为封闭剂，对预聚体进行了封闭研究。着重考察了封闭反应温度、溶剂配 比、促进剂、亚硫酸氢饷用量和浓度、pH 等对封闭率的影响。用Ff-IR 和 DSC 对产物进行了表征分 析，结果显示:在最优条件下，实现了亚硫酸氢铀对端异氨酸醋基的良好封闭，产物的解封温度在 56.3 -68.4 c之间。 关键词:水性聚氨醋;亚硫酸氢铀;封闭反应;解封闭反应 中图分类号:TQ 630.4+3 文献标识码:A 文章编号:0253-4312(2014)10-0038-05 Preparation and Characterization of Waterborne Blocked Polyurethane 1 1 Hu Peng , He 1ρngqiang , Liu Zhon白rang1 ， He Weig1102 (υ1. College 0/ Cωhemicαal/ndlωωωtrηyαnd Enviro 454ω00∞0 ， Chinα; 2. Liming Research /nstitute 0/ Chemical /ndustry , Lωyang ， Henan 471000 , Chinα) Abstract: A polyurethane prepolymer terminated with -NCO groups was synthesized from TDI and PEG-400 as main raw materials , and then the prepolymer was blocked with sodium bisulfate as blocking agent. The effect of blocking temperature , solvent ratio , dosage and mass fraction of sodium bisulfate , promoting agent amount and pH value on blocking rate were dis- cussed. The products were characterized by IT- IR and DSC. The experimental results showed that the good blocking rate of isocyanate by sodium bisulfate could be realized under optimal conditions , additionally the deblocking temperature determined by DSC was approx. 56. 3 - 68.4 C. Key Words: water - bome polyurethane; sodium bisulfate; blocking reaction; deblocking reaction 水性聚氨醋以水为分散介质，具有不燃、气味小、 物)将预聚体中的活泼基团异氨酸醋端基(-N