制备路线对碱性介质氧还原反应电催化剂Ag-MnOxC催化活性的影响.pdfVIP

Qiu-mei WU , et aVTrans. Nonferrous Met. Soc. China 25(2015) 510-519 511 Company. KMn04 , NaBH4 and AgN03 were obtained 但RDE) techniques in Nz or Oz-saturated 0.1 mo l/L from Tianjin Damao Chemical Reagent Factory and NaOH aqueous according ωRef. [17]. 白1e RDE and sodium citrate was 阳chased from Ti叫in Bodi RRDE tests were c缸ried out on CHI 760D Chemical Holding Co. , Ltd. , China. All these chemicals electrochemical workstation (Chenhua Company, China) are of analytic reagent grade and used as received. and computer- controlled bipotentiostat (Pine Company), respectively. A glassy carbon disk electrode cover巳d 2.2 Synthesis of electrocatalysts with a catalyst film was served as the working elec仕ode， TheAg-1也OjC composites with the Ag and MnOx while Pt-wire and HgJHgO electrodes were used as the (MnOz counted as the active material) mass loadings of counter and the reference electrodes, respectively. The 10% and 20% , respectively, were pr叩ared by one-st叩 working electrode was prl ed as follows. 5.0 mg 叩缸 and two-step rout回. For the two-st叩 route， 145.4 mg catalyst was mixed with 2 mL absolute ethanol and k岛位104 was added into the homogeneous aqueous 40μL Nafion solution (5%, mass fraction , DuPont) , then suspension of carbon black (28