丙烯腈_衣康酸共聚物稀溶液的粘度行为_程璐.pdfVIP

DOI :10.1 133/j.cnki .1008 -9357.2008.03.013 　　　　　　 Vol.21 No.3 306 　　　　Journal of Functional Polym ers 2008 9 - 1,2 1 1,2 1 程　璐 , 　王浩静 , 　欧阳琴 , 　郭向云 (1.中国科学院煤炭科学研究所,炭材料重点实验室,太原030001; 2.中国科学院研究生院, 京 1000 9) 　:　采用乌氏粘度计研究了丙烯腈-衣康酸共聚物稀溶液的粘度行为, 探讨了羧基含量对聚 丙烯腈稀溶液偏离Huggins 方程的异常行为的影响。结果表明:随着羧基含量增加, 溶液粘度偏 离Huggins 方程越严重, 要准确测定聚丙烯腈树脂的分子量, 必需适当提高其溶液浓度,避开偏离 区域。 :　丙烯腈-衣康酸共聚物;稀溶液;特性粘度;吸附效应;聚电解质效应 :　O631.　　:　A 　　:　1008-9357(2008)03-0306-06 ViscometricBehavior of Dilute Poly(Acrylonitrile-co-Itaconic Acid )Solution 1,2 1 1,2 1 CHENG Lu , 　WANG Hao-jing , 　O UYANG Qin , 　GUO Xiang-yun (1.Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;2.Graduate University of Chinese Academy of Sciences, Beijing 1000 9, China) Abstract:　The viscometric behavior of dilute poly (acrylonitrile-co-itaconic acid)solution w as studied by means of Ubbelohde viscometer.By investigating the effect of carboxyl content on the deviation to Hug- gins equation in dilute polyacrylonitrile solution, it is found that the deviation becomes more serious w ith carboxyl content increasing .It is suggested that the proper increase of the solution concentration can avoid the deviation zone and obtain a more accurate molecular w eight of the copolymer. Key words:　poly (acrylonitrile-co-itaconic acid );dilute solution;intrinsic viscosity;adsorption effect; polyelectrolyte effect 　　(PAN )。PA N 、 [1] 、、, 。 PAN , , (IA ) [2] 。