稿件编号：201301008 微米级负载型tio2催化剂在光催化-膜分离反应 .docVIP

稿件编号：201301008 微米级负载型TiO2催化剂在光催化-膜分离反应器中研究 费学宁1董业硕，解立平 （1.天津城市建设学院 环境与市政工程系，天津 300384； 3.天津工业大学 环境与化学工程学院天津市中空纤维膜材料与膜过程重点实验室，天津 300160）气量一定的情况下，微米级TiO2催化剂在光催化-膜分离反应器中具有良好的悬浮特性，随着催化剂投加量的增加，悬浮浓度也随之增加光催化反应器底部曝气0.3m3/h、催化剂投加量为1g/L时能够有效降低膜污染，膜底曝气，连续运行h（未加反冲洗后，微米级催化剂纳米TiO2对膜组件的污染程度为膜通量衰减率4.3%37.4%。连续运行h，膜组件依然具有很好的分离特性。 pplication research of micron-scale supported TiO2 catalysts in photocatalysis-membrane reactor Fei Xuening1, Dong Yeshuo1, Chen Lei2, Xie Liping3 （1. Tianjin Key laboratory of Aquatic Science and Technology, Department of Environmental and Municipal Engineering, Tianjin Institute of Urban Construction,Tianjin 300384School of Environmental Science and Engineering ,Tianjin University ,Tianjin 300072; 3.School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin Key Laboratory of Hollow Fiber Membrane Materials and Processes, Tianjin 300387）Abstract: Based on the structural features and membrane separation characteristics of photocatalytic-membrane separation three-phase fluidized bed reactor. In this paper, MCM-41 as the carrier, preparation of micron-scale supported TiO2 catalysts by situ generated. Distribution characteristics, suspension characteristics, separation properties and membrane fouling characteristics of the micron-scale supported TiO2 catalysts in photocatalysis-membrane separation reactor was studied. The results show that:this micron-scale supported TiO2 with good suspension characteristics in case of a certain amount of aeration, and better than nano-TiO2 in photocatalysis-membrane separation reactor. With the increase of catalyst amount, the suspension concentration also increases. Appropriate conditions for aeration of the bottom of the photocatalytic reactor was 0.3m3/h, the catalyst dosage was 1g/L. The suspension concentration of membrane separator was significantly lower than catalyst in the photocatalytic reactor; micron catalyst has lots of excellent characteristics such as :non-sticking, clogging the m